New manganese(II) coordination compounds with 4-{[(1H-pyrrol-2-yl)methylene]amino}-4H-1,2,4-triazole

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Abstract

The reaction of manganese(II) chloride with the azomethine ligand 4-{[(1H-pyrrol-2-yl)methylene]amino}-4H-1,2,4-triazole (HPyrtrz) yielded crystals of the 1D-polymeric compound [MnII(HPyrtrz)(H2O)Cl2]n (I). The addition of the co-ligand 1,10-phenanthroline (phen) to the synthesis of I was found to led to the sequential crystallization of two products, namely, the 1D-polymeric compound [MnII(Phen)Cl2]n (II) and the mononuclear complex [MnII(phen)2Cl2] HPyrtrz (II). Complex III was found to be isolated as a single product in the reaction of compound I with phen or in the reaction of the known complex [MnII(Phen)2Cl2] with HPyrtrz, respectively. The crystal structures of compounds I-III were determined by single-crystal X-ray diffraction (CIF files CCDC № 2339139 (I), № 2344064 (II), № 2339140 (III)). For I and III, antimicrobial activity was studied against E. coli and S. aureus bacterial strains and Penicillium italicum Wehmer mold. According to the temperature dependence of magnetic susceptibility, antiferromagnetic exchange interactions between Mn2+ ions (J = –2.69 cm–1) are realized in compound I. Spectral-luminescent studies showed that HPyrtrz, I and III exhibit blue luminescence in the solid phase.

About the authors

A. A. Bovkunova

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: bazhina@igic.ras.ru
Moscow, Russia

E. S. Bazhina

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: bazhina@igic.ras.ru
Moscow, Russia

M. A. Shmelev

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: bazhina@igic.ras.ru
Moscow, Russia

N. V. Gogoleva

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: bazhina@igic.ras.ru
Moscow, Russia

A. A. Anisimov

HSE University

Email: bazhina@igic.ras.ru
Moscow, Russia

S. Y. Kottsov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: bazhina@igic.ras.ru
Moscow, Russia

K. A. Babeshkin

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: bazhina@igic.ras.ru
Moscow, Russia

N. N. Efimov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: bazhina@igic.ras.ru
Moscow, Russia

M. T. Metlin

Lebedev Physical Institute, Russian Academy of Sciences

Email: bazhina@igic.ras.ru
Moscow, Russia

I. V. Taydakov

Lebedev Physical Institute, Russian Academy of Sciences

Email: bazhina@igic.ras.ru
Moscow, Russia

L. N. Fetisov

North-Caucasian Zonal Scientific Research Veterinary Institute, Federal Rostov Agricultural Research Centre

Email: bazhina@igic.ras.ru
Novocherkassk, Russia

A. E. Svyatogorova

North-Caucasian Zonal Scientific Research Veterinary Institute, Federal Rostov Agricultural Research Centre

Email: bazhina@igic.ras.ru
Novocherkassk, Russia

A. A. Zubenko

North-Caucasian Zonal Scientific Research Veterinary Institute, Federal Rostov Agricultural Research Centre

Email: bazhina@igic.ras.ru
Novocherkassk, Russia

M. A. Kiskin

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: bazhina@igic.ras.ru
Moscow, Russia

I. L. Eremenko

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Author for correspondence.
Email: bazhina@igic.ras.ru
Moscow, Russia

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