Synthesis and structure of iron(II) complex compounds with 1-methyl-2-pyridine-2-yl-1H- and 1-methyl-2-phenyliminomethyl-1H-benzimidazoles and boron cluster anions [BH]2– (n = 10, 12)

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

The paper studies reactions of iron(II) complexation with benzimidazole derivatives L (L1 = C13N3H11, L2 = C15N3H13) in the presence of salts of boron cluster anions [BnHn]2– (n = 10, 12). The obtained complex compounds of the general formula [FeL3][BnHn] are characterized by elemental analysis and IR spectroscopy. The structure of complex [FeL13][B10H10] is determined by single-crystal X-ray diffraction (CCDС № 2432134). The distorted octahedral environment of the Fe atom is formed by the imidazole and pyridine N atoms of three L1 molecules. In the crystal, the [FeL13]2+ complex has a meridional configuration. The Fe–N bond lengths for imidazolium nitrogen atoms are in the range of 1.954(8)–1.980(6) Å, and for pyridine nitrogen atoms 1.977(7)–2.011(8) Å.

About the authors

V. V. Avdeeva

Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: avdeeva.varvara@mail.ru
Moscow, 119991 Russia

A. S. Kubasov

Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: avdeeva.varvara@mail.ru
Moscow, 119991 Russia

S. E. Nikiforova

Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: avdeeva.varvara@mail.ru
Moscow, 119991 Russia

O. N. Belousova

Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: avdeeva.varvara@mail.ru
Moscow, 119991 Russia

E. A. Malinina

Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: avdeeva.varvara@mail.ru
Moscow, 119991 Russia

N. T. Kuznetsov

Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Author for correspondence.
Email: avdeeva.varvara@mail.ru
Moscow, 119991 Russia

References

  1. Greenwood N.N., Earnshaw A. Chemistry of the elements. school of chemistry, Butterworth–Heinemann (U.K.): University of Leeds, 1997.
  2. Boron science: new technologies and applications / Ed. Hosmane N.S. CRC Press, 2012.
  3. Boron-based compounds: potential and emerging applications in medicine / Eds. Hey-Hawkins E., Viñas Teixidor C. John Wiley & Sons Ltd., 2018. https://doi.org/10.1002/9781119275602
  4. Zhizhin K.Y., Zhdanov A.P., Kuznetsov N.T. // Russ. J. Inorg. Chem. 2010. V. 55. № 14. P. 2089. https://doi.org/10.1134/S0036023610140019
  5. Sivaev I.B., Prikaznov A.V., Naoufal D. // Collect. Czech. Chem. Commun. 2010. V. 75. P. 1149. https://doi.org/10.1135/cccc2010054
  6. Mahfouz N., Abi Ghaida F., El Hajj F. et al. // ChemistrySelect. 2022. V. 7. Art. e202200770. https://doi.org/10.1002/slct.202200770
  7. Matveev E.Y., Avdeeva V.V., Zhizhin K.Yu. et al. // Inorganics. 2022. V. 10. P. 238. https://doi.org/10.3390/inorganics10120238
  8. Zhang Y., Cai Z., Chen Z. et al. // Chin. J. Struct. Chem. 1982. V. 1. P. 46.
  9. Zhang Y., Chen Z., Cai Z. et al. // Chin. J. Struct. Chem. 1982. V. 2. P. 201.
  10. Avdeeva V.V., Vologzhanina A.V., Goeva L.V. еt al. // Z. Anorg. Allg. Chem. 2014. V. 640. № 11. P. 2149. https://doi.org/10.1002/zaac.201400137
  11. Короленко С.Е., Авдеева В.В., Малинина Е.А. и др. // Коорд. химия. 2020. Т. 46. № 5. С. 259 (Korolenko S.E., Avdeeva V.V., Malinina E. A. et al. // Russ. J. Coord. Chem. 2020. V. 45. No. 5. P. 297). https://doi.org/10.1134/S1070328420050024
  12. Nguyen Duc Van. Thesis: New salt-like dodecahydro-closo-dodecaborates and efforts for the partial hydroxylation of [B12H12]2– anions. Stuttgart: Institut fűr Anorganische Chemie der Universitat, 2009.
  13. Avdeeva V.V., Kubasov A.S., Korolenko S.E. et al. // Polyhedron. 2022. V. 217. P. 115740. https://doi.org/10.1016/j.poly.2022.115740
  14. Sirivardane U., Chu S.S.C., Hosmane N.S. et al. // Acta Crystallogr. 1989. p. 333. https://doi.org/10.1107/S0108270188010716
  15. Nikiforova S.E., Kubasov A.S., Son A.G. et al. // Inorg. Chim. Acta. 2023. V. 557. P. 121654. https://doi.org/10.1016/j.ica.2023.121654
  16. Ivanova A.D., Lavrenova L.G., Korotaev E.V. et al. // Russ. J. Inorg. Chem. 2020. V. 65. P. 1687. https://doi.org/10.1134/S0036023620110078
  17. Lavrenova L.G., Dyukova I.I., Korotaev E.V. et al. // Russ. J. Inorg. Chem. 2020. V. 65. P. 30. https://doi.org/10.1134/S0036023620010106
  18. Ivanova A.D., Lavrenova L.G., Korotaev E.V. et al. // Russ. J. Inorg. Chem. 2022. V. 67. P. 1158. https://doi.org/10.1134/S0036023622080174
  19. Lavrenova L.G., Shakirova O.G. // Russ. J. Inorg. Chem. 2023. V. 68. P. 690. https://doi.org/10.1134/S0036023623600764
  20. Kravchenko E.A., Gippius A.A., Polyakova I.N. et al. // ZAAC. 2017. V. 643. P. 1939. https://doi.org/10.1002/zaac.201700293
  21. Voloshin Y.Z., Varzatskii O.A., Zhizhin K.Y. et al. // Russ. Chem. Bull. 2006. V. 55. P. 22. https://doi.org/10.1007/s11172-006-0210-6
  22. Авдеева В.В., Вологжанина А.В., Гоева Л.В. и др. // Докл. РАН. 2015. Т. 461. № 6. С. 664 (Avdeeva V.V., Vologzhanina A.V., Goeva L.V. et al. // Dokl. Chem. 2015. V. 461 P. 96). https://doi.org/10.1134/S0012500815040035
  23. Авдеева В.В., Полякова И.Н., Гоева Л.В. и др. // Журн. неорган. химии. 2015. Т. 60. № 7. С. 9019 (Avdeeva V.V., Polyakova I.N., Goeva L.V. et al. // Russ. J. Inorg. Chem. 2015. V. 60. P. 817). https://doi.org/10.1134/S0036023615070037
  24. Miller H.C., Miller N.E., Muetterties E.L. // J. Am. Chem. Soc. 1963. V.85. P. 3885. https://doi.org/10.1021/ja00906a033
  25. Greenwood N.N., Morris J.H. // Proc. Chem. Soc. 1963. № 11. P. 338.
  26. Бурлов А.С., Анцышкина А.С., Садиков Г.Г. и др. // Коорд. химия. 2010. Т. 36. № 12. С. 918 (Russ. J. Coord. Chem. 2010. V. 36. № 12. P. 906). https://doi.org/10.1134/S1070328410120079
  27. SAINT. Madison (WI, USA): Bruker AXS Inc., 2018.
  28. Krause L., Herbst-Irmer R., Sheldrick G.M., Stalke D.J. // Appl. Crystallogr. 2015. V. 48. № 1. P. 3. https://doi.org/10.1107/S1600576714022985
  29. Sheldrick G.M. // Acta Crystallogr. C. 2015. V. 71. P. 3. https://doi.org/10.1107/S2053229614024218
  30. Dolomanov O.V., Bourhis L.J., Gildea R.J. et al. // J. Appl. Cryst. 2009. V. 42. P. 339. https://doi.org/10.1107/S0021889808042726
  31. Spackman P.R., Turner M.J., McKinnon J.J. et al. // J. Appl. Crystallogr. 2021. V. 54. P. 1006. https://doi.org/10.1107/S1600576721002910
  32. Keikha M., Pourayoubi M., Tarahhomi A. et al. // Z. Krist. Mater. 2017. V. 232. № 6. P. 453.
  33. Spackman M.A., Jayatilaka D. // CrystEngComm. 2009. V. 11. № 1. P. 19.

Supplementary files

Supplementary Files
Action
1. JATS XML
Download

Copyright (c) 2025 Russian Academy of Sciences

Согласие на обработку персональных данных

 

Используя сайт https://journals.rcsi.science, я (далее – «Пользователь» или «Субъект персональных данных») даю согласие на обработку персональных данных на этом сайте (текст Согласия) и на обработку персональных данных с помощью сервиса «Яндекс.Метрика» (текст Согласия).