Chemical transformations of bimetallic complex [Pd(OOCMe)4Mn] in reactions with 1,10-phenanthroline, pivalic acid and 5-nitro-1,10-phenantroline

E. A. Sosunov; Сосунов Е. А.; A. D. Maksimova; Максимова А. Д.; I. A. Yakushev; Якушев И. А.; N. K. Ogarkova; Огаркова Н. К.; M. N. Vargaftik; Варгафтик М. Н.; A. S. Popova; Попова А. С.

doi:10.31857/S0132344X23700330

Chemical transformations of bimetallic complex [Pd(OOCMe)4Mn] in reactions with 1,10-phenanthroline, pivalic acid and 5-nitro-1,10-phenantroline

Authors: Sosunov E.A.¹, Maksimova A.D.¹, Yakushev I.A.¹, Ogarkova N.K.¹, Vargaftik M.N.¹, Popova A.S.¹
Affiliations:
1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia
Issue: Vol 49, No 12 (2023)
Pages: 772-781
Section: Articles
URL: https://journals.rcsi.science/0132-344X/article/view/162373
DOI: https://doi.org/10.31857/S0132344X23700330
EDN: https://elibrary.ru/HINRJX
ID: 162373

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Abstract

A number of new bimetallic acetate and pivalate complexes of the Pd–Mn system have been synthesized and structurally characterized. The starting complex [Pd(OOCMe)4Mn] reacts with N donor ligands such as 1,10-phenanthroline to form [Pd(OOCMe)4Mn(phen)]·MeCN (I) (CIF file CCDC no. 2217716). The reactions of substitution of acetate bridges for pivalate bridges in heterometallic carboxylate Pd–Mn complexes have been studied; It has been shown that complete replacement of all acetate bridges with pivalate bridges is possible both in the heterometallic complex (I), in which there is a ligand coordinated to an additional metal atom, with the formation of the compound [Pd(Piv)4Mn(phen)]·C6H6, (II) ( CIF file CCDC No. 2217717), structurally close to the original acetate complex, and in the acetate complex [Pd(OOCMe)4Mn]. The heterometallic pivalate cocrystallizate [Pd(Piv)4Mn 2HPiv] (III) obtained in the latter case (CIF file CCDC No. 2217718) is capable of reacting with 5-nitro-1,10-phenanthroline to form the complex [Pd(Piv)4Mn( nphen)] (IV) (CIF file CCDC No. 2217719).

Keywords

palladium, manganese, heterometallic complexes, synthesis, X-ray diffraction analysis, crystal chemistry

References

Buchwalter P., Rosé J., Braunstein P. // Chem. Rev. 2015. V. 115. № 1. P. 28.
Kozitsyna N.Yu., Nefedov S.E., Yakushev I.A. et al. // Mendeleev Commun. 2007. V. 17. № 5. P. 261.
Khramov E., Belyakova O., Murzin V. et al. // Z. Anorg. Allg. Chem. 2014. V. 640. № 12–13. P. 2577.
Ershov B.G., Anan’ev A.V., Abkhalimov E.V. et al. // Nanotechnologies Russ. 2011. V. 6. № 5–6. P. 323.
Cherkashina N.V., Churakov A.V., Yakushev I.A. et al. // Russ. J. Coord. Chem. 2019. V. 45. № 4. P. 253. https://doi.org/10.1134/S107032841904002X
Garkul I.A., Zadesenets A.V., Korolkov I.V. et al. // J. Struct. Chem. 2020. V. 61. № 5. P. 719.
Garkul’ I.A., Zadesenets A.V., Plyusnin P.E. et al. // Russ. J. Inorg. Chem. 2020. V. 65. № 10. P. 1571. https://doi.org/10.1134/S003602362010006X
Smirnova N.S., Khramov E.V., Stolarov I.P. et al. // Intermetallics. 2021. V. 132. P. 107160.
Nefedov S.E., Vargaftik M.N., Moiseev I.I. // Inorg. Chem. Commun. 2006. V. 9. № 7. P. 755.
Yakushev I.A., Sosunov E.A., Makarevich Yu.E. et al. // J. Struct. Chem. 2022. V. 63. № 12. P. 103431.
Pasynskii A.A., Shapovalov S.S., Skabitskii I.V. et al. // Russ. J. Coord. Chem. 2016. V. 42. № 9. P. 608. https://doi.org/10.31857/S0132344X22030069
Nefedov S.E., Yakushev I.A., Kozitsyna N.Yu. et al. // Inorg. Chem. Commun. 2007. V. 10. № 8. P. 948.
Nefedov S.E., Kozitsyna N.Yu., Akhmadullina N.S. et al. // Inorg. Chem. Commun. 2011. V. 14. № 4. P. 554.
Nefedov S.E., Kozitsyna N.Yu., Vargaftik M.N. et al. // Polyhedron. 2009. V. 28. № 1. P. 172.
Ho P.-H., Hung C.-C., Wang Y.-H. et al. // Asian J. Org. Chem. 2019. V. 8. № 2. P. 275.
Pasynskii A.A., Shapovalov S.S. // Russ. J. Coord. Chem. 2016. V. 42. № 9. P. 574. https://doi.org/10.1134/S1070328416090050
Shapovalov S.S., Gordienko A.V., Pasynskii A.A. et al. // Russ. J. Coord. Chem. 2011. V. 37. № 6. P. 447. https://doi.org/10.1134/S1070328411050125
Yakushev I.A., Dyuzheva M.A., Stebletsova I.A. et al. // Russ. J. Coord. Chem. 2022. V. 48. № 3. P. 153. https://doi.org/10.1134/S107032842203006X
Popova A.S., Ogarkova N.K., Shapovalov S.S. et al. // Mendeleev Commun. 2022. V. 32. № 5. P. 576.
Shmelev M.A., Gogoleva N.V., Makarov D.A. et al. // Russ. J. Coord. Chem. 2020. V. 46. № 1. P. 1. https://doi.org/10.1134/S1070328420010078
Nefedov S.E., Perova E.V., Yakushev I.A. et al. // Inorg. Chem. Commun. 2009. V. 12. № 6. P. 454.
Nefedov S.E., Kushan E.V., Uvarova M.A. et al. // Inorg. Chim. Acta. 2013. V. 395. P. 104.
Nefedov S.E., Uvarova M.A., Golubnichaya M.A. et al. // Russ. J. Inorg. Chem. 2014. V. 59. № 7. P. 733. https://doi.org/10.1134/S0036023614070171
Kozitsyna N.Yu., Nefedov S.E., Dolgushin F.M. et al. // Inorg. Chim. Acta 2006. V. 359. № 7. P. 2072.
Perrin D.D., Armarego W.L.F. Purification of Laboratory Chemicals. Oxford: Pergamon, 1988.
APEX3, SAINT and SADABS. Madison (WI, USA): Bruker AXS Inc., 2016.
Krause L., Herbst-Irmer R., Sheldrick G.M. et al. // J. Appl. Crystallogr. 2015. V. 48. № 1. P. 3.
Sheldrick G.M. // Acta Crystallogr. A. 2015. V. 71. № 1. P. 3.
Sheldrick G.M. // Acta Crystallogr. C. 2015. V. 71. № 1. P. 3.
Dolomanov O.V., Bourhis L.J., Gildea R.J. et al. // J. Ap-pl. Crystallogr. 2009. V. 42. № 2. P. 339.
Huang G.-H., Li J.-M., Huang J.-J. et al. // Chem.- Eur. J. 2014. V. 20. № 18. P. 5240.
Akhmadullina N.S., Cherkashina N.V., Kozitsyna N.Yu. et al. // Inorg. Chim. Acta. 2009. V. 362. № 6. P. 1943.
Pinsky M., Avnir D. // Inorg. Chem. 1998. V. 37. № 21. P. 5575.
Cirera J., Ruiz E., Alvarez S. // Chem. - Eur. J. 2006. V. 12. № 11. P. 3162.
Janjić G.V., Petrović P.V., Ninković D.B. et al. // J. Mol. Model. 2011. V. 17. № 8. P. 2083.
Yakushev I.A., Stebletsova I.A., Cherkashina N.V. et al. // J. Struct. Chem. 2021. V. 62. № 9. P. 1411.
Lord R.C., Merrifield R.E. // J. Chem. Phys. 1953. V. 21. № 1. P. 166.