Email this article SOLVOTHERMAL SYNTHESIS, STRUCTURE, AND PROPERTIES OF CADMIUM(II)-ORGANIC COORDINATION POLYMER CONTAINING CARBOXYL GROUPS
- Authors: Xu B.1, Yao W.1, Yu S.2,3, Samsonenko D.G.2, Fedin V.P.2,3, Gao E.1
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Affiliations:
- China-Russian Institute of Engineering Materials Chemistry, School of Chemical Engineering, University of Science and Technology Liaoning, Anshan, 114051, China
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090, Novosibirsk, Russia
- Novosibirsk State University, 630090, Novosibirsk, Russia
- Issue: Vol 49, No 12 (2023)
- Pages: 731-736
- Section: Articles
- URL: https://journals.rcsi.science/0132-344X/article/view/162364
- DOI: https://doi.org/10.31857/S0132344X23600133
- EDN: https://elibrary.ru/LPTJNX
- ID: 162364
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Abstract
Under the conditions of solvothermal synthesis, a new metal-organic coordination polymer of the composition Cd[H2L] (I, H4L = 4,4'-([2,2'-bipyridine]-6,6'-diylbis(oxy))diphthalic acid). According to X-ray diffraction analysis, each Cd(II) cation binds four organic ligands: one via the coordination of the chelate bipyridyl fragment, two via the bidentate coordination of deprotonated COO groups, and one more via the monodentate coordination of the protonated carboxylate group. The obtained three-dimensional metal-organic framework does not contain free space capable of including guest molecules. Compound I was characterized by powder X-ray diffraction, IR spectroscopy, elemental (C, H, N) and thermogravimetric analyses, and luminescence spectra were recorded for it.
About the authors
B. Xu
China-Russian Institute of Engineering Materials Chemistry, School of Chemical Engineering, University of Science and Technology Liaoning, Anshan, 114051, China
Email: cluster@niic.nsc.ru
Китай, Аньшань
W. Yao
China-Russian Institute of Engineering Materials Chemistry, School of Chemical Engineering, University of Science and Technology Liaoning, Anshan, 114051, China
Email: cluster@niic.nsc.ru
Китай, Аньшань
S. Yu
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090, Novosibirsk, Russia; Novosibirsk State University, 630090, Novosibirsk, Russia
Email: cluster@niic.nsc.ru
Россия, Новосибирск; Россия, Новосибирск
D. G. Samsonenko
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090, Novosibirsk, Russia
Email: cluster@niic.nsc.ru
Россия, Новосибирск
V. P. Fedin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090, Novosibirsk, Russia; Novosibirsk State University, 630090, Novosibirsk, Russia
Email: cluster@niic.nsc.ru
Россия, Новосибирск; Россия, Новосибирск
E. Gao
China-Russian Institute of Engineering Materials Chemistry, School of Chemical Engineering, University of Science and Technology Liaoning, Anshan, 114051, China
Author for correspondence.
Email: cluster@niic.nsc.ru
Китай, Аньшань
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