Furancarboxylate Coordination Polymers of Gd3+ and Eu3+: Synthesis, Structural Variations, and Biological Properties
- Authors: Uvarova M.A.1, Lutsenko I.A.1, Shmelev M.A.1, Bekker O.B.2, Kiskin M.A.1, Eremenko I.L.1
-
Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
- Vavilov Institute of General Genetics, Russian Academy of Sciences, Moscow, Russia
- Issue: Vol 49, No 9 (2023)
- Pages: 543-552
- Section: Articles
- URL: https://journals.rcsi.science/0132-344X/article/view/137310
- DOI: https://doi.org/10.31857/S0132344X23600029
- EDN: https://elibrary.ru/WATJKU
- ID: 137310
Cite item
Abstract
A series of polymer complexes of Gd(III) and Eu(III) with 3-furancarboxylic (HFur) and 5-nitro-
2-furancarboxylic (HNfur) acids differed in the composition and coligands presented by solvent molecules
(CH3OH/C2H5OH/H2O) is synthesized: [Gd(Fur)3(CH3OH)(C2H5OH)]n (I), [Gd(Nfur)3(CH3OH)2]n·
CH3CN (II), [Eu(Fur)3(C2H5OH)]n (III), and [Eu(Nfur)3(H2O)2]n·3CH3CN (IV). According to the X-ray
diffraction (XRD) data, all complexes are 1D coordination polymers in which the lanthanide cation has the
coordination number 8 (LnO8) to form the environment as a doubly augmented triangular prism (I, II) or a
square antiprism (III, IV). The supramolecular levels of the polymers are stabilized due to intra- and intermolecular
hydrogen bonds between the coordinated solvent molecules and O atoms of the chelate-bound
anions of the acid and via two types of noncovalent C–H…O and N–O…π interactions that significantly contribute
to an additional stabilization of the crystal packings. The biological properties of complexes I, II, and
IV are studied with respect to the model nonpathogenic strain Mycolicibacterium smegmatis.
About the authors
M. A. Uvarova
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
Email: yak_marin@mail.ru
Россия, Москва
I. A. Lutsenko
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
Email: yak_marin@mail.ru
Россия, Москва
M. A. Shmelev
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
Email: shmelevma@yandex.ru
Россия, Москва
O. B. Bekker
Vavilov Institute of General Genetics, Russian Academy of Sciences, Moscow, Russia
Email: yak_marin@mail.ru
Россия, Москва
M. A. Kiskin
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
Email: yak_marin@mail.ru
Россия, Москва
I. L. Eremenko
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
Author for correspondence.
Email: yak_marin@mail.ru
Россия, Москва
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