Complexes of Cu(II), Co(II), and Zn(II) Terephthalates with Hydroxyalkylamines

D. A. Zav’yalova; Завьялова Д. А.; Yu. A. Kondratenko; Кондратенко Ю. А.; A. A. Zolotarev; Золотарев А. А.; V. L. Ugolkov; Уголков В. Л.; T. A. Kochina; Кочина Т. А.

doi:10.31857/S0132344X22600655

Complexes of Cu(II), Co(II), and Zn(II) Terephthalates with Hydroxyalkylamines

作者: Zav’yalova D.A.¹^,2, Kondratenko Y.A.¹, Zolotarev A.A.³, Ugolkov V.L.¹, Kochina T.A.¹
隶属关系:
1. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, St. Petersburg, Russia
2. St. Petersburg State Technological Institute (Technical University), St. Petersburg, Russia
3. Institute of Earth Sciences, St. Petersburg State University, St. Petersburg, Russia
期: 卷 49, 编号 8 (2023)
页面: 474-484
栏目: Articles
URL: https://journals.rcsi.science/0132-344X/article/view/137309
DOI: https://doi.org/10.31857/S0132344X22600655
EDN: https://elibrary.ru/SALKEI
ID: 137309

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详细

The reactions of Cu(II), Co(II), and Zn(II) terephthalates with hydroxyalkylamines (tris(2-hydroxyethyl)amine, bis(2-hydroxyethyl)amine, tris(hydroxymethyl)aminomethane, and bis(2-hydroxyethyl)aminotris(hydroxymethyl)methane) are studied for the first time. The structures and properties of the synthesized complexes are studied by IR spectroscopy, electronic absorption spectroscopy, mass spectrometry, and elemental and thermal analyses. The structure of the binuclear heteroligand [Cu2(TEA)2(Tph)]n·H2O complex is studied by single-crystal X-ray diffraction (XRD) (CIF file CCDC no. 2224437).

关键词

metal-organic frameworks, coordination polymers, hydrometallatranes, hydroxyalkylamines, terephthalic acid, crystal structure

参考

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