Reactions of Triangular Molybdenum and Tungsten Clusters with Tetrabromocatechol

P. A. Petrov; Петров П. А.; E. A. Filippova; Филиппова Е. А.; V. R. Giniyatullin; Гиниятуллин В. Р.; T. S. Sukhikh; Сухих Т. С.; D. G. Sheven’; Шевень Д. Г.; A. L. Gushchin; Гущин А. Л.; M. N. Sokolov; Соколов М. Н.

doi:10.31857/S0132344X22600485

Reactions of Triangular Molybdenum and Tungsten Clusters with Tetrabromocatechol

Authors: Petrov P.A.¹, Filippova E.A.¹, Giniyatullin V.R.², Sukhikh T.S.¹, Sheven’ D.G.¹, Gushchin A.L.¹, Sokolov M.N.¹
Affiliations:
1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2. Novosibirsk State University, Novosibirsk, Russia
Issue: Vol 49, No 8 (2023)
Pages: 451-457
Section: Articles
URL: https://journals.rcsi.science/0132-344X/article/view/137304
DOI: https://doi.org/10.31857/S0132344X22600485
EDN: https://elibrary.ru/SAABSD
ID: 137304

Cite item

Full Text

Open Access
Restricted Access

Access granted
Restricted Access

Subscription Access

Abstract
About the authors
References
Supplementary files
Statistics

Abstract

The reaction of cluster complex (nBu4N)2[Mo3Se7Br6] with tetrabromocatechol (H2Tbc) in the presence of Et3N and Ph4PBr results in the formation of (Ph4P)2[Mo3Se7(Tbc)3]∙2MeOH (Ia∙2MeOH). Under the same conditions, the tungsten analogue (nBu4N)2[W3S7Br6] is completely or partly destroyed to give the complex (Ph4P)(Et3NH)[WO2(Tbc)2] (II). The structures of Ia·2MeOH and II were established by X-ray diffraction analysis (CCDC nos. 2213900 and 2213901, respectively). The redox properties of complex Ia and related (Ph4P)2[Mo3S7(Tbc)3] (Ib) and (Ph4P)2[Mo3S7(Tcc)3] (Ic) (Tcc is tetrachlorocatecholate) were also studied by cyclic voltammetry.

Keywords

molybdenum, tungsten, clusters, redox-active ligands, cyclic voltammetry

References

Гущин А.Л., Ларичева Ю.А., Соколов М.Н., Llusar R. // Успехи химии. 2018. Т.87. С. 670 (Gushchin A.L., Laricheva Y.A., Sokolov M.N., Llusar R. // Russ. Chem. Rev. 2018. V. 87. P. 670). https://doi.org/10.1070/RCR4800
Llusar R., Vicent C. // Coord. Chem. Rev. 2010. V. 254. P. 1534.
Llusar R., Uriel S., Vicent C. et al. // J. Am. Chem. Soc. 2004. V. 126. P. 12071.
Gushchin A.L., Llusar R., Vicent C. et al. // Eur. J. Inorg. Chem. 2013. P. 2615.
Гущин А.Л., Абрамов П.А., Пересыпкина Е.В., Соколов М.Н. // Коорд. химия. 2013. Т. 39. С. 8 (Gushchin A.L., Abramov P.A., Peresypkina E.V., Sokolov M.N. // Russ. J. Coord. Chem. 2013. V. 39. P. 6). https://doi.org/10.1134/S1070328413010041
Falvello L.R., Llusar R., Triguero S., Vicent C. // Chem. Commun. 2009. P. 3440.
Petrov P.A. // J. Cluster Sci. 2017. V. 28. P. 1815.
Петров П.А., Афонин М.Ю., Наумов Д.Ю. и др. // Коорд. химия. 2015. Т. 41. С. 34 (Petrov P.A., Afonin M.Yu., Naumov D.Yu. et al. // Russ. J. Coord. Chem. 2015. V. 41. P. 31) https://doi.org/10.1134/S1070328415010078
Matsumoto T., Yano H., Wakizaka M. et al. // Bull. Chem. Soc. Jpn. 2015. V. 88. P. 74.
Petrov P.A., Nadolinny V.A., Bogomyakov A.S., Sukhikh T.S. // New J. Chem. 2018. V. 42. P. 12349.
Sokolov M.N., Abramov P.A., Gushchin A.L. et al. // Inorg. Chem. 2005. V. 44. P. 8116.
Gushchin A.L., Sokolov M.N., Peresypkina E.V. et al. // Eur. J. Inorg. Chem. 2008. P. 3964.
Вировец А.В., Гущин А.Л., Абрамов П.А. и др. // Журн. структур. химии. 2006. Т. 47. С. 332 (Virovets A.V., Gushchin A.L., Abramov P.A. et al. // J. Struct. Chem. 2006. V. 47. P. 326). https://doi.org/10.1007/s10947-006-0303-y
Gushchin A.L., Ooi B.-L., Harris P. et al. // Inorg. Chem. 2009. V. 48. P. 3832.
APEX2 (version 1.08), SAINT (version 7.03), SADABS (version 2.11), SHELXTL (version 6.12). Madison (WI, USA): Bruker AXS Inc., 2004.
Sheldrick G.M. // Acta Crystallogr. A. 2015. V. 71. P. 3.
Sheldrick G.M. // Acta Crystallogr. C. 2015. V. 71. P. 3.
Dolomanov O.V., Bourhis L.J., Gildea R.J. et al. // J. A-ppl. Cryst. 2009. V. 42. P. 339.
DeLearie L.A., Pierpont C.G. // Inorg. Chem. 1988. V. 27. P. 3842.
Llusar R., Triguero S., Vicent C. et al. // Inorg. Chem. 2005. V. 44. P. 8937.