Lutetium Cyclopentadienyl Complex with the 2,6-Di-tert-Butylanthracene Dianion

D. M. Roitershtein; Ройтерштейн Д. М.; K. A. Lyssenko; Лысенко К. А.; I. E. Nifant’ev; Нифантьев И. Э.; M. E. Minyaev; Миняев М. Е.

doi:10.31857/S0132344X22600497

Lutetium Cyclopentadienyl Complex with the 2,6-Di-tert-Butylanthracene Dianion

Authors: Roitershtein D.M.¹^,2, Lyssenko K.A.³, Nifant’ev I.E.¹^,2^,3, Minyaev M.E.²
Affiliations:
1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia
2. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia
3. Moscow State University, Moscow, Russia
Issue: Vol 49, No 6 (2023)
Pages: 367-374
Section: Articles
URL: https://journals.rcsi.science/0132-344X/article/view/137293
DOI: https://doi.org/10.31857/S0132344X22600497
EDN: https://elibrary.ru/UQIJUF
ID: 137293

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Abstract
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Abstract

The reaction of 2,6-di(tert-butyl)anthracene with potassium graphite and monocyclopentadienyllutetium dichloride tetrahydrofuranate in THF gave the anthracenide complex [(η5-C5H5)Lu(η2-2,6-tBu2C14H8)(THF)2] (I), which was studied by X-ray diffraction (CCDC no. 2215512). Complex I crystallizes in the orthorhombic space group P212121. The structural rigidity of the Lu(O)2Cp(anthracene) crystallographic node was demonstrated. The retention of the structure of complex I in solution was confirmed by NMR techniques.

Keywords

rare earth elements, lutetium, anthracene, X-ray diffraction analysis

References

Evans W.J. // Polyhedron 1987. V. 6. P. 803.
Richardson G.M., Douair I., Cameron S.A. et al. // Chem. Eur. J. 2021. V. 27. P. 13144.
Huang W., Khan S.I., Diaconescu P.L. // J. Am. Chem. Soc. 2011. V. 133. P. 10410.
Huang W., Dulong F., Wu T. // Nature Commun. 2013. V. 4. Art. 1448.
Huang W., Abukhalil P.M., Khan S.I., Diaconescu P.L. // Chem. Commun. 2014. V. 50. P. 5221.
Fryzuk M.D., Jafarpour L., Kerton F.M. // Angew. Chem. Int. Ed. 2000. V. 39. P. 767.
Huang W., Diaconescu P.L. // Chem. Commun. 2012. V. 48. P. 2216.
Huang W., Diaconescu P.L. // Eur. J. Inorg. Chem. 2013. P. 4090.
Roitershtein D.M., Ellern A.M., Antipin M.Y. et al. // Mendeleev Commun. 1992. V. 2. P. 118.
Protchenko A.V., Zakharov L.N., Bochkarev M.N., Struchkov Y.T. // J. Organomet. Chem. 1993. V. 447. P. 209.
Roitershtein D.M., Romanenkov A.V., Lyssenko K.A. et al. // Russ. Chem. Bull. 2007. V. 56. P. 1749.
Ghana P., Hoffmann A., Spaniol T.P., Okuda J. // Chem. Eur. J. 2020. V. 26. P. 10290.
Roitershtein D.M., Rybakova L.F., Petrov E.S. // J. Organomet. Chem. 1993. V. 460. P. 39.
Cassani M.C., Gun’ko Yu.K., Hitchcock P.B. et al. // Organometallics. 1999. V. 18. P. 5539.
Stephan D.W., Erker G. // Angew. Chem. Int. Ed. 2015. V. 54. P. 6400.
Stephan D.W. // Science. 2016. V. 354. Art. aaf7229.
Jupp A.R., Stephan D.W. // Trends Chem. 2019. V. 1. P. 35.
Thiele K.-H., Bambirra S., Schumann H., Hemling H. // J. Organomet. Chem. 1996. V. 517. P. 161.
Evans W.J., Gonzales S.L., Ziller J.W. // J. Am. Chem. Soc. 1994. V. 116. P. 2600.
Edelmann F., Poremba P. // Synthetic Methods of Organometallic and Inorganic Chemistry / Eds. Edelmann F.T., Herrmann W.A. Stuttgart (Germany): Verlag, 1997. P. 34.
Panda T.K., Gamer M.T., Roesky P.W. // Organometallics. 2003. V. 22. P. 877.
Ottmers D.M., Rase H.F. // Carbon. 1966. V. 4. P. 125.
Wang J., Wan W., Jiang H. et al. // Org. Lett. 2010. V. 12. P. 3874.
APEX-III. Madison (WI, USA): Bruker AXS Inc., 2019.
Sheldrick G.M. // Acta Crystallogr. A. 2015. V. 71. P. 3.
Sheldrick G.M. // Acta Crystallogr. C. 2015. V. 71. P. 3.
Macrae C.F., Sovago I., Cottrell S.J. et al. // J. Appl. Cryst. 2020. V. 53. P. 226.
Fedushkin I.L., Bochkarev M.N., Dechert S., Schumann H. // Chem. Eur. J. 2001. V. 7. P. 3558.
Ellis J.E., Minyaev M.E., Nifant’ev I.E., Churakov A.V. // Acta Crystallogr. C. 2018. V. 74. P. 769.
Bogdanovic B., Janke N., Kruger C. // Angew. Chem. Int. Ed. 1985. V. 24. P. 960.
Lehmkuhl H., Shakoor A., Mehler K., Kruger C. et al. // Chem. Ber. 1985. V. 118. P. 4239.
Alonso T., Harvey S., Junk P.C. et al. // Organometallics. 1987. V. 6. P. 2110.
Raymond K.N., Eigenbrot C. // Acc. Chem. Res. 1980. V. 13. P. 276.