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Adducts of Sterically Hindered Tellurium Catecholate with Ethers
- Authors: Petrov P.A.1
-
Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
- Issue: Vol 49, No 6 (2023)
- Pages: 354-359
- Section: Articles
- URL: https://journals.rcsi.science/0132-344X/article/view/137288
- DOI: https://doi.org/10.31857/S0132344X22600448
- EDN: https://elibrary.ru/UQDOJA
- ID: 137288
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Abstract
Adducts of tellurium(IV) 3,6-di-tert-butyl catecholate (Te(Cat36)2) with 1,2-dimethoxyethane (Dme), bis(2-methoxy)ethyl ether (diglyme), and crown ether 18-crown-6 (18c6) ([Te(Cat36)2(Dme)]2 (I), [Te(Cat36)2(diglyme)] (II), and [Te2(Cat36)4(18c6)] (III), respectively) are synthesized and characterized by X-ray diffraction (XRD) (CIF files CCDC nos. 2208717 (I), 2208718 (II), and 2208719 (III)). The complexes are also characterized by NMR (1H, 125Te) and IR spectroscopy.
About the authors
P. A. Petrov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
Author for correspondence.
Email: panah@niic.nsc.ru
Россия, Новосибирск
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