Bromoantimonates(III) vs. Bromobismuthates(III): Differences in the Tendency for the Formation of Polynuclear Complexes

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Abstract

Pyridine-based Sb(III) bromide complexes with doubly charged cations, (PyC3)3[Sb2Br9]2 (I), (PyC4)[Sb2Br8] (II), (PyC5)2[α-Sb4Br16] (III), (PyC6)2[Sb2Br10] (IV), (4-MePyC2)2[Sb2Br10] (V), (4‑MePyC3)2[α-Sb4Br16] (VI), and (4-MePyC5)2[α-Sb4Br16] (VII), were synthesized and characterized by X-ray diffraction (CCDC nos. 2204718–2204724). The structures of these compounds were compared with the structures of related bromobismuthates(III).

About the authors

A. N. Usoltsev

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

Email: adonin@niic.nsc.ru
Россия, Новосибирск

I. V. Korol’kov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

Email: adonin@niic.nsc.ru
Россия, Новосибирск

S. A. Adonin

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

Author for correspondence.
Email: adonin@niic.nsc.ru
Россия, Новосибирск

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