Novel Cobalt Bis-o-semiquinonato Complexes with Bidentate N-Donor Ligands

A. A. Zolotukhin; Золотухин А. А.; M. P. Bubnov; Бубнов М. П.; R. V. Rumyantsev; Румянцев Р. В.; G. K. Fukin; Фукин Г. К.; A. S. Bogomyakov; Богомяков А. С.; V. K. Cherkasov; Черкасов В. К.

doi:10.31857/S0132344X22700165

Novel Cobalt Bis-o-semiquinonato Complexes with Bidentate N-Donor Ligands

Authors: Zolotukhin A.A.¹, Bubnov M.P.¹, Rumyantsev R.V.¹, Fukin G.K.¹, Bogomyakov A.S.², Cherkasov V.K.¹
Affiliations:
1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia
2. International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
Issue: Vol 49, No 3 (2023)
Pages: 174-182
Section: Articles
URL: https://journals.rcsi.science/0132-344X/article/view/137276
DOI: https://doi.org/10.31857/S0132344X22700165
EDN: https://elibrary.ru/BOCLWY
ID: 137276

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Abstract

Two new cobalt bis-o-semiquinonato complexes, (Pyz-Phen)Co(3,6-DBSQ)2 (I) and (Bpyz)Co(3,6-DBSQ)2 (II) (Pyz-Phen = pyrazino[2,3-f][1,10]phenanthroline, Bpyz = bipyrazine, 3,6-DBSQ = 3,6-di-tert-butyl-o-benzoquinone radical anion), were synthesized. According to X-ray diffraction data, both complexes have a trigonal-prismatic geometry of the inner coordination sphere. The distribution of C–O and Co–O bond lengths, which reflects the valence state of the metal and the ligands, indicates that the complexes are formed by cobalt(II) surrounded by two semiquinone radical anions. The results of magnetochemical measurements show that the pyrazino[2,3-f][1,10]phenanthroline complex is a derivative of low-spin divalent cobalt, whereas its bipyrazine structural analogue is a high-spin cobalt(II) derivative.

Keywords

cobalt complexes, o-semiquinones, trigonal prism, magnetic properties

References

Pierpont C.G. // Coord. Chem. Rev. 2001. V. 216–217. P. 99. https://doi.org/10.1016/S0010-8545(01)00309-5
Tezgerevska T., Alley K.G., Boskovic C. // Coord. Chem. Rev. 2014. V. 268. P. 23. https://doi.org/10.1016/j.ccr.2014.01.014
Золотухин А.А., Бубнов М.П., Черкасов В.К. и др. // Коорд. химия. 2018. 44. № 2. С. 123 (Zolotukhin A.A., Bubnov M.P., Cherkasov V.K. et al. // Russ. J. Coord. Chem. 2018. V. 44. P. 272). https://doi.org/10.7868/S0132344X18020056
Buchanan R.M., Pierpont C.G. // J. Am. Chem. Soc. 1980. V. 102. P. 4951. https://doi.org/10.1021/ja00535a021
Абакумов Г.А., Черкасов В.К., Бубнов М.П. и др. // Докл. РН. 1993. Т. 328. № 3. С. 332 (Abakumov G.A., Cherkasov V.K., Bubnov M.P. et al. // Dokl. Akad. Nauk. 1993. V. 328. P. 332). https://doi.org/S0020-1693(22)00023-8/h0080
Roux C., Adams D.M., Itie J.P. et al. // Inorg. Chem. 1996. V. 35. P. 2846. https://doi.org/10.1021/ic951080o
Markevtsev I.N., Monakhov M.P., Platonov V.V. et al. // J. Magn. Magn. Mater. 2006. V. 300. P. e407. https://doi.org/10.1016/j.jmmm.2005.10.134
Yokoyama T., Okamoto K., Nagai K. et al. // Chem. Phys. Lett. 2001. V. 345. P. 272. https://doi.org/10.1016/S0009-2614(01)00888-0
Francisco T.M., Gee W.J., Shepherd H.J. // J. Phys. Chem. Lett. 2017. V. 8. № 19. P. 4774. https://doi.org/10.1021/acs.jpclett.7b01794
Lukyanov A. Yu. Bubnov M.P., Skorodumova N.A. et al. // Solid State Sci. 2015. V. 48. P. 13. https://doi.org/10.1016/j.solidstatescienes.2015.06.011
Jung O.-S., Jo D.H., Lee Y.-A. et al. // Inorg. Chem. 1997. V. 36. P. 19. https://doi.org/10.1021/ic961214d
Zolotukhin A.A., Bubnov M.P., Arapova A.V. et al. // Inorg. Chem. 2017. V. 56. P. 14751. https://doi.org/10.1021/acs.inorgchem.7b02597
Adams D.M., Dei A., Rheingold A.L. et al. // J. Am. Chem. Soc. 1993. V. 115. P. 8221. https://doi.org/10.1021/ja00071a035
Арапова А.В., Бубнов М.П., Абакумов Г.А. и др. // Журн. физ. химии. 2009. Т. 83. № 8. С. 1417.
Jung O.-S., Pierpont C.G. // Inorg. Chem. 1994. V. 33. P. 2227. https://doi.org/10.1021/ic00088a027
Protasenko N.A., Poddel’sky A.I., Bogomyakov A.S. et al. // Polyhedron. 2013. V. 49. P. 239. https://doi.org/10.1016/j.poly.2012.10.016
Zolotukhin A.A., Bubnov M.P., Bogomyakov A.S. et al. // Inorg. Chim. Acta. 2020. V. 502. 119346. https://doi.org/10.1016/j.ica.2019.119346
Gomez-Coca S., Cremades E., Aliaga-Alcalde N. et al. // J. Am. Chem. Soc. 2013. V. 135. P. 7010. https://doi.org/10.1021/ja4015138
Novikov V.V., Pavlov A.A., Nelyubina Y.V. et al. // J. Am. Chem. Soc. 2015. V. 137. P. 9792. https://doi.org/10.1021/jacs.5b05739
Perrin D.D., Armarego W.L.F., Perrin D.R. Purification of Laboratory Chemicals. Oxford: Pergamon Press, 1980.
Litvinenko A.S., Mikhaleva E.A., Kolotilov S.V., Pavlishchuk V.V. // Theor. Exp. Chem. 2011. V. 46. P. 422. https://doi.org/10.1007/s11237-011-9174-1
Rigaku Oxford Diffraction. CrysAlis Pro Software System. Version 1.171.38.46. Wroclaw (Poland): Rigaku Corporation, 2015.
SAINT. Data Reduction and Correction Program. Madison (WI, USA): Bruker AXS, 2014.
Kraus L., Herbst-Irmer R., Sheldrick G.M., Stalke D. // J. Appl. Crystallogr. 2015. V. 48. P. 3. https://doi.org/10.1107/S1600576714022985
Sheldrick G.M. // Acta Crystallogr. A. 2015. V. 71. P. 3. https://doi.org/10.1107/S2053273314026370
Sheldrick G.M. // Acta Crystallogr. C. 2015. V. 71. P. 3. https://doi.org/10.1107/S2053229614024218
Pierpont C.G., Buchanan R.M. // Coord. Chem. Rev. 1981. V. 38. P. 45. https://doi.org/10.1016/S0010-8545(00)80499-3
Brown S.N. // Inorg. Chem. 2012. V. 51. P. 1251. https://doi.org/10.1021/ic202764j
Adams D.M., Dei A., Rheingold A.L. et al. // Angew. Chem. Int. Ed. 1993. V. 32. P. 880. https://doi.org/10.1002/anie.199308801
Wang J.-H., Dai J.-W., Li Z.-Y. et al. // New J. Chem. 2020. V. 44. P. 8471. https://doi.org/10.1039/D0NJ00767F
Janiak C. // Dalton Trans. 2000. P. 3885. https://doi.org/10.1039/b003010o
Guda A.A., Chegerev M., Starikov A.G. et al. // J. Phys.: Condens. Matter. 2021. V. 33. 215405. https://doi.org/10.1088/1361-648X/abe650
Protasenko N.A., Poddel’sky A.I. // Theor. Exp. Chem. 2020. V. 56. P. 338. https://doi.org/10.1007/s11237-020-09663-1
Graf M., Wolmershauser G., Kelm H. et al. // Angew. Chem. Int. Ed. 2010. V. 49. P. 950. https://doi.org/10.1002/anie.200903789
Фарус О.А., Балашев К.П., Иванов М.А. и др. // Журн. общ. химии. 2006. T. 76. С. 328.
Kawanishi Y., Kitamura N., Tazuke S. // Inorg. Chem. 1989. V. 28. P. 2968. https://doi.org/10.1021/ic00314a019
Hendrickson D.N., Pierpont C.G. // Top. Curr. Chem. 2004. V. 234. P. 63. https://doi.org/10.1007/b95413
Jung O.-S., Pierpont C.G. // J. Am. Chem. Soc. 1994. V. 116. P. 1127. https://doi.org/10.1021/ja00082a043