Углерод-минеральные материалы из сапропеля как носители для катализаторов гидродехлорирования
- Autores: Терехова Е.1, Бельская О.1
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Afiliações:
- Институт катализа СО РАН
- Edição: Volume 97, Nº 1 (2024)
- Páginas: 4-13
- Seção: Катализ
- URL: https://journals.rcsi.science/0044-4618/article/view/259627
- DOI: https://doi.org/10.31857/S0044461824010018
- EDN: https://elibrary.ru/CLXTTR
- ID: 259627
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Resumo
В работе представлены результаты исследования возможности применения углерод-минеральных материалов, полученных из доступного сырья сапропеля, в качестве носителей для палладиевых катализаторов реакции гидродехлорирования хлорбензола. Селективное образование целевого продукта бензола было достигнуто при достаточно низком содержании палладия (0.5 мас%) в мягких условиях жидкофазной реакции (2 МПа, 90°С) при конверсии хлорбензола 50–60% (время реакции 5 ч). Показано, что катализатор на носителе из сапропеля минерального типа после его активации в среде водяного пара, обладающий мезопористой структурой, продемонстрировал активность выше, чем катализаторы на основе органического сапропеля.
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Sobre autores
Елена Терехова
Институт катализа СО РАН
Email: e.terechova@ihcp.ru
ORCID ID: 0000-0001-8555-8043
Центр новых химических технологий, к.х.н.
Rússia, 644040, г. Омск, ул. Нефтезаводская, д. 54Ольга Бельская
Институт катализа СО РАН
Autor responsável pela correspondência
Email: e.terechova@ihcp.ru
ORCID ID: 0000-0002-7650-880X
Центр новых химических технологий, к.х.н.
Rússia, 644040, г. Омск, ул. Нефтезаводская, д. 54Bibliografia
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