Reactivity of olefin functions of dicyclopentadiene in the Diels-Alder reaction with thionylaniline
- 作者: Ilyushkina E.1, Veremeychik Y.1, Lodochnikova O.2,3, Plemenkov V.3
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隶属关系:
- I. Kant Baltic Federal University
- A. E. Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”
- A. M. Butlerov Institute of Chemistry, Kazan Federal (Volga Region) University
- 期: 卷 93, 编号 5 (2023)
- 页面: 659-663
- 栏目: Articles
- URL: https://journals.rcsi.science/0044-460X/article/view/145042
- DOI: https://doi.org/10.31857/S0044460X23050013
- EDN: https://elibrary.ru/DAMLHS
- ID: 145042
如何引用文章
详细
The sulfonamide with a benzothiazine moiety was synthesized by a Diels-Alder reaction of thionylaniline with dicyclopentadiene. The prepared adduct was oxidized to the appropriate sulfonamide with a benzothiazine moiety. The molecular and crystal structure of the sulfonamide obtained was determined by the single crystal X-ray diffraction analysis. A higher reactivity of the the olefin function of the norbornene fragment was found; and the formation of two structural isomers was revealed.
作者简介
E. Ilyushkina
I. Kant Baltic Federal University
Ya. Veremeychik
I. Kant Baltic Federal University
Email: verem_yana@mail.ru
O. Lodochnikova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”;A. M. Butlerov Institute of Chemistry, Kazan Federal (Volga Region) University
V. Plemenkov
A. M. Butlerov Institute of Chemistry, Kazan Federal (Volga Region) University
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