Synthesis and some properties of magnesium and zinc tetra-3-(4-bromophenoxy)phthalocyanines

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Abstract

The work describes the synthesis of non-periphery substituted Zn(II), Mg(II) phthalocyanines complexes obtained from 3-(4-bromophenoxy)phthalonitrile. The influence of the metal complex on the spectral and acid-base properties of the obtained compounds was shown. The quantum yield and fluorescence lifetime of the synthesized metal complexes were determined.

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About the authors

T. V. Tikhomirova

Ivanovo State University of Chemistry and Technology

Author for correspondence.
Email: tararjkina@mail.ru
ORCID iD: 0000-0002-7920-3921
Russian Federation, Ivanovo 153000

S. S. Tonkova

Ivanovo State University of Chemistry and Technology

Email: tararjkina@mail.ru
ORCID iD: 0000-0001-6701-7833
Russian Federation, Ivanovo 153000

A. S. Vashurin

Ivanovo State University of Chemistry and Technology; Kurnakov Institute of General and Inorganic Chemistry

Email: tararjkina@mail.ru
ORCID iD: 0000-0003-2239-8753
Russian Federation, Ivanovo 153000; Moscow, 119071

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Supplementary files

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2. Fig. 1. Electronic absorption spectra of solutions of compound 2b in chloroform (1, cMRs = 7.8·10-6 mol/l) and DMFA (2, cMRs = 6.9·10-6 mol/l).

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3. 2. Electronic absorption spectra of zinc tetra-4-(4-bromophenoxy)phthalocyanine solutions in chloroform (1, cMRs = 4.5·10-6 mol/l) and DMFA (2, cMRs = 3.2·10-6 mol/l).

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4. Fig. 3. Changes in the electronic absorption spectra during titration of a solution of complex 2a (CMR = 7.67·10-5 mol/l) in toluene with trifluoroacetic acid (a) and a general view of the titration curve at 694 nm (b).

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5. Fig. 4. Changes in the electronic absorption spectra during titration of a solution of zinc tetra-4-(4-bromophenoxy)phthalocyanine (cMRs = 7.61·10-5 mol/l) in toluene with trifluoroacetic acid (a) and a general view of the titration curve at 681 nm (b).

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6. Scheme 1.

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7. Scheme 2.

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