Synthesis of Copper-Nickel Bimetallic Nanoparticles by Caprylate Reduction in Benzyl Alcohol
- Authors: Titkov A.I.1, Gerasimov E.Y.2, Vorobyov A.M.1, Malbakhova I.A.1, Borisenko T.A.1, Logutenkо O.A.1
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Affiliations:
- Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch of the Russian Academy of Sciences
- G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences
- Issue: Vol 94, No 3 (2024)
- Pages: 450-460
- Section: Articles
- URL: https://journals.rcsi.science/0044-460X/article/view/261514
- DOI: https://doi.org/10.31857/S0044460X24030151
- EDN: https://elibrary.ru/FXYSFQ
- ID: 261514
Cite item
Abstract
Based on the process of joint reduction of copper and nickel caprylates in benzyl alcohol at 185°C, a simple method for the synthesis of bimetallic copper and nickel nanoparticles was developed. The prepared bimetallic nanoparticles may be of interest for creating new compositions of electrically conductive inks and pastes for 2D and 3D printing. The resulting nanoparticles were characterized by X-ray phase analysis, scanning and transmission electron microscopy in combination with energy-dispersive X-ray spectroscopy. The prepared copper and nickel nanoparticles are single- or two-phase bimetallic solid solutions of various compositions. The effect of the phase composition of bimetallic powders on their resistance to oxidation was studied. It was shown that an increase in the nickel content in the composition leads to a decrease in the degree of nanoparticles oxidation. The proposed method is one-step, does not require the use of additional stabilizers and reducing agents, the synthesis is carried out in one-pot and is easily scalable. The method can also be used to obtain other bi- and polymetallic nanoparticles.
Keywords
Full Text
About the authors
A. I. Titkov
Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch of the Russian Academy of Sciences
Email: ologutenko@solid.nsc.ru
ORCID iD: 0000-0003-0835-9985
Russian Federation, Novosibirsk, 630128
E. Yu. Gerasimov
G. K. Boreskov Institute of Catalysis, Siberian Branch of the RussianAcademy of Sciences
Email: ologutenko@solid.nsc.ru
ORCID iD: 0000-0002-3230-3335
Russian Federation, Novosibirsk, 630090
A. M. Vorobyov
Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch of the Russian Academy of Sciences
Email: ologutenko@solid.nsc.ru
ORCID iD: 0000-0002-4896-3821
Russian Federation, Novosibirsk, 630128
I. A. Malbakhova
Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch of the Russian Academy of Sciences
Email: ologutenko@solid.nsc.ru
ORCID iD: 0000-0003-4193-3571
Russian Federation, Novosibirsk, 630128
T. A. Borisenko
Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch of the Russian Academy of Sciences
Email: ologutenko@solid.nsc.ru
ORCID iD: 0000-0003-0341-8755
Russian Federation, Novosibirsk, 630128
O. A. Logutenkо
Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch of the Russian Academy of Sciences
Author for correspondence.
Email: ologutenko@solid.nsc.ru
ORCID iD: 0000-0003-1523-5446
Russian Federation, Novosibirsk, 630128
References
- Wu W. // Nanoscale. 2017. Vol. 9. P. 7342. doi: 10.1039/C⁷NR01604B
- Huang Q., Zhu Y. // Adv. Mater. Technol. 2019. Vol. 4. N 5. P. 1. doi: 10.1002/admt.201970029
- Nanotechnology for food packaging. Materials, processing technologies, and safety issues / Eds M. Cerqueira, J. Lagaron, L. Castro, A. Vicente. Amsterdam: Elsevier, 2018. 332 p.
- Rao V.K., Abhinav K.V., Karthik P.S., Singh S.P. // RSC Adv. 2015. Vol. 5. P. 77760. doi: 10.1039/C⁵ra12013f
- Magdassi S., Grouchko M., Kamyshny A. // Materials. 2010. Vol. 3. N 9. P. 4626. doi: 10.3390/ma3094626
- Songping W. // Microelectronics J. 2007. Vol. 38. N 1. P. 41. doi: 10.1016/j.mejo.2006.09.013
- Songping W., Li J., Jing N., Zhenou Z., Song L. // Intermetallics. 2007. Vol. 15. N 10. P. 1316. doi 10.1016/ j.intermet.2007.04.001
- Sharma M.K., Qi D., Buchner R.D., Scharmach W.J., Papavassiliou V., Swihart M.T. // ACS Appl. Mater. Interfaces. 2014. Vol. 6. N 16. P. 13542. doi: 10.1021/am5026853
- Seemala B., Cai C.M., Kumar R., Wyman C.E., Christopher Ph. // ACS Sustain. Chem. Eng. 2018. Vol. 6. N 2. P. 2152. doi: 10.1021/acssuschemeng.7b03572
- Pastor-Pérez L., Gu S., Sepúlveda-Escribano A., Rein T.R. // Int. J. Hydrog. Energy. 2019. Vol. 44. N 8. P. 4011. doi: 10.1016/j.ijhydene.2018.12.127
- Meneses-Brassea B.P., Borrego E.A., Blazer D.S., Sanad M.F., Pourmiri S., Gutierrez D.A., Varela-Ramirez A., Hadjipanayis G.C., El-Gendy A.A. // Nanomaterials. 2020. Vol. 10. N 10. P. 1988. doi: 10.3390/nano10101988
- Ban I., Stergar J., Drofenik M., Ferk G., Makovec D. // J. Magn. Magn. Mater. 2011. Vol. 323. N 17. P. 2254. doi: 10.1016/j.jmmm.2011.04.004
- Toshima, N., Yonezawa, T. // New J. Chem. 1998. Vol. 22. N 11. P. 1179. https://doi.org/10.1039/A805753B
- Ferk G., Stergar J., Makovec D., Hamler A., Jaglicic Z., Drofenik M., Ban I. // J. Alloys Compd. 2015. Vol. 648. N 5. P. 53. doi: 10.1016/j.jallcom.2015.06.067
- Stergar J., Ferk G., Ban I., Drofenik M., Hamler A., Jagodic M., Makovec D. // J. Alloys Compd. 2013. Vol. 576. P. 220. doi: 10.1016/j.jallcom.2013.04.130
- Wen M., Liu Q.Y., Wang Y.F., Zhu Y.Z., Wu Q.S. // Colloids Surf. (A). 2008. Vol. 318. P. 238. doi 10.1016/ j.colsurfa.2007.12.041
- Пугачев В.М., Захаров Ю.А., Васильева О.В., Карпушкина Ю.В., Додонов В.Г. // Химия в интересах устойчивого развития. 2015. Т. 23. С. 169. doi: 10.15372/KhUR²0150211
- Fiévet F., Ammar-Merah S., Brayner R., Chau F., Giraud M., Mammeri F., Peron J., Piquemal J.-Y., Sicard L., Viau G. // Chem. Soc. Rev. 2018. Vol. 47. P. 5187. doi: 10.1039/C⁷CS00777A
- Parimaladevi R., Parvathi V.P., Lakshmi S.S., Umadev M. // Mater. Lett. 2018. Vol. 211. P. 82. doi 10.1016/ j.matlet.2017.09.097
- Bonet F., Grugeon S., Dupont L., Herrera Urbina R., Guery C., Tarascon J.M. // J. Solid State Chem. 2003. Vol. 172. P. 111. doi: 10.1016/S0022-4596(02)00163-9
- Niederberger M., Bartl M.H., Stucky G.D. // J. Am. Chem. Soc. 2002. Vol. 124, N 46. P. 13642–13643. https://doi.org/10.1021/ja027115i
- Ляхов Н.З., Юхин Ю.М., Тухтаев Р.К., Мищенко К.В., Титков А.И., Логутенко О.А. // Химия в интересах устойчивого развития. 2014. Т. 22. № 4. С. 409.
- Юхин Ю.М., Титков А.И., Логутенко О.А., Мищенко К.В., Ляхов Н.З. // ЖОХ. 2017. Т. 87. № 12. С. 2057; Yukhin Yu.M., Titkov A.I., Logutenko O.A., Mishchenko K.V., Lyakhov N.Z. // Russ. J. Gen. Chem. 2017. Vol. 87. N 12. P. 2870. doi: 10.1134/S1070363217120180
- Юхин Ю.М., Логутенко О.А., Титков А.И., Ляхов Н.З. // Хим. технол. 2016. Т. 17. № 7. С. 314; Yukhin Yu.M., Logutenko O.A., Titkov A.I., Lyakhov N.Z. // Theor. Found. Chem. Eng. 2017. Vol. 51. N 5. P. 809. doi: 10.1134/S0040579517050232
- Титков А.И., Логутенко О.А., Булина Н.В., Юхин Ю.М., Ляхов Н.З. // Хим. технол. 2016. Т. 17. № 5. С. 202; Titkov A.I., Logutenko O.A., Bulina N.V., Yukhin Y.M., Lyakhov N.Z. // Theor. Found. Chem. Eng. 2017. Vol. 51. N 4. P. 557. doi: 10.1134/S004057951704014
- Titkov A.I., Logutenko O.A., Vorobyov A.M., Gerasimov E.Yu., Shundrina I.K., Bulina N.V., Lyakhov N.Z. // Colloids Surf. (A). 2019. Vol. 577. P. 500. doi 10.1016/ j.colsurfa.2019.06.008
- Tsybulya S.V., Cherepanova S.V., Soloviyova L.P. // J. Struct. Chem. 1996. Vol. 37, N 2. 332. https://doi.org/10.1007/bf02591064
- Пирсон У.Б. Кристаллохимия и физика металлов и сплавов. М.: Мир, 1977. T. 1. 419 c.