Email this article Properties of Hydrolyzed Polyalumotris(acetylacetonato)ethylsiloxane
- Authors: Shapkin N.P.1, Pervakov K.A.1, Fedorets A.N.1, Lembikov A.O.1, Dran’kov A.N.1, Savchenko V.G.1
-
Affiliations:
- Far Eastern Federal University
- Issue: Vol 94, No 3 (2024)
- Pages: 440-449
- Section: Articles
- URL: https://journals.rcsi.science/0044-460X/article/view/261512
- DOI: https://doi.org/10.31857/S0044460X24030146
- EDN: https://elibrary.ru/FXZMYM
- ID: 261512
Cite item
Open Access
Access granted
Abstract
The work is devoted to the study of the structural and sorption properties of metal exchangers obtained under conditions of extraction by hydrochloric acid (1:2) of the product of interaction of tris(3-chlorosulfenyl)-2,4-aluminum pentanedionate with vinyl trichlorosilane. The reaction was considered using two organic solvents – chloroform and toluene. A comparison of diffractometric parameters, elemental analysis, NMR spectra, thermogravimetric curves, as well as surfaces (SEM) and internal structure of isolated substances was presented. The capacity of the products with respect to Fe³⁺ is on the order of 7.1 mg·eq/g.
Full Text
About the authors
N. P. Shapkin
Far Eastern Federal University
Email: pervakov.ka@dvfu.ru
Russian Federation, Vladivostok, 690922
K. A. Pervakov
Far Eastern Federal University
Author for correspondence.
Email: pervakov.ka@dvfu.ru
ORCID iD: 0009-0002-5233-1592
Russian Federation, Vladivostok, 690922
A. N. Fedorets
Far Eastern Federal University
Email: pervakov.ka@dvfu.ru
Russian Federation, Vladivostok, 690922
A. O. Lembikov
Far Eastern Federal University
Email: pervakov.ka@dvfu.ru
ORCID iD: 0000-0003-0436-0612
Russian Federation, Vladivostok, 690922
A. N. Dran’kov
Far Eastern Federal University
Email: pervakov.ka@dvfu.ru
ORCID iD: 0000-0002-2215-7987
Russian Federation, Vladivostok, 690922
V. G. Savchenko
Far Eastern Federal University
Email: pervakov.ka@dvfu.ru
Russian Federation, Vladivostok, 690922
References
- Сергиенко Н.В., Транкина Е.С., Польщикова Н.В., Корлюков А.А. // Коорд. хим. 2021. Т. 47. № 6. С. 344; Sergienko N.V., Trankina E.S., Polshchikova N.V., Korlyukov A.A. // Russ. J. Coord. Chem. 2021. Vol. 47. N 6. P. 382. doi: 10.1134/S1070328421060063.
- Херинг Р. Хелатообразующие ионообменники. М.: Мир, 1971. 279 c.
- Свистунова И.В. Дис. ... канд. хим. наук. Владивосток: ДВФУ, 1998. 101 с.
- Аликовский А.В., Крижаненко Г.А., Капустина А.А., Телешова В.П., Шапкин Н.П. // Колл. ж. 1988. Т. 50. № 3. С. 551.
- Andropova U., Serenko O., Tebeneva N., Tarasenkov A., Askadskii A., Afanasyev E., Novikov L., Chernik V., Voronina E., Muzafarov A. // Polym. Degrad. Stab. 2021. Vol. 183. Article ID 109424. doi: 10.1016/j.polymdegradstab.2020.109424
- Parshina M.S., Tarasenkov A.N., Aysin R.R., Tebeneva N.A., Buzin M.I., Afanasyev E.S., Serenko O.A., Muzafarov A.M. // J. Polym. Sci. 2021. Vol. 138. N 36. P. 1. doi: 10.1002/app.50918
- Yoon C.S., Ji D.S. // Fibers Polym. 2003. Vol. 4. N 4. P. 210.
- Шапкин Н.П., Свистунов Г.М., Шапкина В.Я. // Высокомол. соед. (A). 1989. Т. 31. С. 573.
- Pervakov K.A., Shapkin N.P., Razov V.I., Fedorets A.N. // Silicon. 2024. P. 2509. doi: 10.1007/s12633-024-02861-9
- Петров А.Д., Миронов В.Ф., Пономаренко В.А., Чернышов Е.А. Синтез кремнийорганических мономеров. М., 1961. 551 c.
- Miller R.L., Boyer R.F., Heijboer J. // J. Polym. Sci. (A). 1984. Vol. 22. N 12. P. 2043. doi: 10.1002/pol.1984.180221203
- Андрианов К.А., Кононов А.М., Цванкин Д.Я. // Высокомол. соед. (Б). 1968. Т. 10. № 5. С. 320.
- Kluiber R.W. // J. Am. Chem. Soc. 1961. Vol. 83. N 14. P. 3030. doi: 10.1021/ja01475a013
Supplementary files
