Synthesis and Structure of Barium Hexaferrite BaFe12–xInxO19 (x = 0–1)
- Authors: Punda A.Y.1, Gafarov K.P.1, Zhivulin V.E.1, Chernukha A.S.1,2, Zykova A.R.1, Gudkova S.A.1,2, Pesin L.A.1, Vyatkin G.P.1, Vinnik D.A.1,2,3
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Affiliations:
- South Ural State University (National Research University)
- Moscow Institute of Physics and Technology (National Research University)
- St. Petersburg State University
- Issue: Vol 94, No 2 (2024)
- Pages: 285-291
- Section: Articles
- URL: https://journals.rcsi.science/0044-460X/article/view/260349
- DOI: https://doi.org/10.31857/S0044460X24020149
- EDN: https://elibrary.ru/GUJHYL
- ID: 260349
Cite item
Abstract
This study presents the results of the synthesis and examination of indium-substituted barium hexaferrite samples with the formula BaFe12–xInxO19. The ferrites were obtained via a solid state synthesis method. The substitution level of indium, represented by x(In), was varied from 0 to 1 in 0.25 increments. The stoichiometric formulas of the compounds were calculated using the EDS data. The powder X-ray diffraction analysis indicated that all samples form a single crystalline phase with the M-type hexaferrite structure. Parameters of the crystal unit cell were calculated from powder diffraction data. An expansion of the crystal lattice parameters was observed as iron was substituted with indium, from x = 0 to x = 0.84. The Curie temperatures of the synthesized ferrites were determined using differential scanning calorimetry (DSC) method. It is established that the Curie temperature decreases from 452 to 292°C with In content growth from x = 0 to x = 0.84 in the BaFe12–xInxO19.
Full Text
About the authors
A. Yu. Punda
South Ural State University (National Research University)
Author for correspondence.
Email: pundaai@susu.ru
Russian Federation, Chelyabinsk, 454080
K. P. Gafarov
South Ural State University (National Research University)
Email: pundaai@susu.ru
Russian Federation, Chelyabinsk, 454080
V. E. Zhivulin
South Ural State University (National Research University)
Email: pundaai@susu.ru
Russian Federation, Chelyabinsk, 454080
A. S. Chernukha
South Ural State University (National Research University); Moscow Institute of Physics and Technology (National Research University)
Email: pundaai@susu.ru
Russian Federation, Chelyabinsk, 454080; Dolgoprudny, 141701
A. R. Zykova
South Ural State University (National Research University)
Email: pundaai@susu.ru
Russian Federation, Chelyabinsk, 454080
S. A. Gudkova
South Ural State University (National Research University); Moscow Institute of Physics and Technology (National Research University)
Email: pundaai@susu.ru
Russian Federation, Chelyabinsk, 454080; Dolgoprudny, 141701
L. A. Pesin
South Ural State University (National Research University)
Email: pundaai@susu.ru
Russian Federation, Chelyabinsk, 454080
G. P. Vyatkin
South Ural State University (National Research University)
Email: pundaai@susu.ru
Russian Federation, Chelyabinsk, 454080
D. A. Vinnik
South Ural State University (National Research University); Moscow Institute of Physics and Technology (National Research University); St. Petersburg State University
Email: pundaai@susu.ru
Russian Federation, Chelyabinsk, 454080; Dolgoprudny, 141701; St. Petersburg, 199034
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