Structural Features of d2-Rhenium(V) Monomeric Octahedral Dioxocomplexes with Tridentate-Chelate, Monodentate Ligands [ReO2(Ltri)(Lmono)], and Tetradentate-Chelate Ligands [ReO2(Ltetra)] (A Review)

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Abstract

Molecular geometry features of 21 structurally characterized mononuclear octahedral dioxocomplexes of d2-rhenium(V) with mono-, tri- and tetradentate ligands [ReO2(Ltri)(Lmono)], [ReO2(Ltetra)] are discussed. In eleven cases, multiple-bonded Ooxo ligands are arranged in trans-positions to each other with OoxoReOoxo angles ranging within 172.9–180°. In ten structures, the ReO2 unit adopts cis-configuration with OoxoReOoxo angles vary within 106.7–124.8°. Re atoms possess either trans-octahedral coordination environment ReOoxo2X4 (X = N, P, As, O) or cis-structure ReOoxo2N2O2. Bonds Re=Ooxo in monomeric octahedral dioxocompounds d2-Re(V) (mean length 1.772 Å) are significantly longer those observed for monooxocomplexes d2-Re(V) (1.676–1.699 Å).

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V. S. Sergienko

N. S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Author for correspondence.
Email: sergienko@igic.ras.ru
Russian Federation, Moscow, 119991

A. V. Churakov

N. S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: sergienko@igic.ras.ru
ORCID iD: 0000-0003-3336-4022
Russian Federation, Moscow, 119991

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Supplementary files

Supplementary Files
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2. Fig. 1. Structure of [ReO2 (PNN)I] (3) and [ReO2) (Me3Tacn) (H2O)]+ (5) complexes according to RSA data.

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3. Fig. 2. The structure of the complexes [ReO2(BPMEN)]+ (7), [ReO2(BmdmPMEN)]+ (8), cis-[ReO2(Pyxn)]+ (14) and trans-[ReO2(Pyxn)]+ (15) according to RSA data.

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4. Fig. 3. Structure of [ReO2(Tpp)]+ (19) and [ReO2(DTBP) complexes]+ (21) according to the RSA.

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