Email this article Effect of the Nature of Nitrogen-Containing Organic Base on Destruction of Octa(4-tert-butylphenyl)tetrapyrazinoporphyrazine
- Authors: Petrov O.A.1, Volzhankina K.A.1
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Affiliations:
- Ivanovo State University of Chemistry and Technology
- Issue: Vol 94, No 2 (2024)
- Pages: 245-252
- Section: Articles
- URL: https://journals.rcsi.science/0044-460X/article/view/260333
- DOI: https://doi.org/10.31857/S0044460X24020098
- EDN: https://elibrary.ru/GUYQBZ
- ID: 260333
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Abstract
The properties of octa(4-tert-butylphenyl)tetrapyrazinoporphyrazine in 2-methylpyridine were studied. During the acid-base interaction of molecules, a kinetically stable complex was formed with proton transfer. The addition of morpholine, piperidine, n-butylamine, and diethylamine to 2-methylpyridine led to the destruction of this complex, unlike the addition of tert-butylamine and triethylamine. The influence of the proton-accepting ability and spatial structure of the nitrogen-containing base, as well as the basicity of the medium, on the process of the tetrapyrazinoporphyrazine macrocycle decomposition was considered, and a destruction scheme was proposed.
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About the authors
O. A. Petrov
Ivanovo State University of Chemistry and Technology
Author for correspondence.
Email: poa@isuct.ru
ORCID iD: 0000-0003-3424-7135
Russian Federation, Ivanovo, 153000
K. A. Volzhankina
Ivanovo State University of Chemistry and Technology
Email: poa@isuct.ru
ORCID iD: 0009-0009-9355-3600
Russian Federation, Ivanovo, 153000
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