Email this article Electron Transfer in Reaction of 12H-Quinoxalino[2,3-b]phenoxazines with π-Acceptors
- Authors: Ivakhnenko E.P.1, Knyazev P.A.1, Makarova N.I.1, Demidov O.P.2, Starikov A.G.1, Minkin V.I.1
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Affiliations:
- Institute of Physical and Organic Chemistry, Southern Federal University
- North-Caucasus Federal University
- Issue: Vol 94, No 2 (2024)
- Pages: 216-224
- Section: Articles
- URL: https://journals.rcsi.science/0044-460X/article/view/260325
- DOI: https://doi.org/10.31857/S0044460X24020072
- EDN: https://elibrary.ru/GVAIUD
- ID: 260325
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Abstract
Using the reaction of 2,4-di-(tert-butyl)-12-(4-methoxyphenyl)-10-methoxy-12H-quinoxalino[2,3-b]phenoxazine with π-electron acceptors such as tetracyanoquinodimethane and 3,6-di-(tert-butyl)-o-quinone) as an example it was shown that derivatives of this N,O-pentaheterocyclic system are effective electron donors that, under mild conditions, carry out electron transfer reactions with the formation of stable cation and anion radical structures.
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About the authors
E. P. Ivakhnenko
Institute of Physical and Organic Chemistry, Southern Federal University
Author for correspondence.
Email: ivakhnenko@sfedu.ru
ORCID iD: 0000-0003-0338-6466
Russian Federation, Rostov-on-Don, 344091
P. A. Knyazev
Institute of Physical and Organic Chemistry, Southern Federal University
Email: ivakhnenko@sfedu.ru
ORCID iD: 0000-0001-6627-8329
Russian Federation, Rostov-on-Don, 344091
N. I. Makarova
Institute of Physical and Organic Chemistry, Southern Federal University
Email: ivakhnenko@sfedu.ru
ORCID iD: 0000-0002-7196-9842
Russian Federation, Rostov-on-Don, 344091
O. P. Demidov
North-Caucasus Federal University
Email: ivakhnenko@sfedu.ru
ORCID iD: 0000-0002-3586-0487
Russian Federation, Stavropol, 355017
A. G. Starikov
Institute of Physical and Organic Chemistry, Southern Federal University
Email: ivakhnenko@sfedu.ru
ORCID iD: 0000-0002-5613-6308
Russian Federation, Rostov-on-Don, 344091
V. I. Minkin
Institute of Physical and Organic Chemistry, Southern Federal University
Email: ivakhnenko@sfedu.ru
ORCID iD: 0000-0001-6096-503X
Russian Federation, Rostov-on-Don, 344091
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