Photochemical production of molecular hydrogen in the presence of substituted acridine salts
- 作者: Dolganov A.1, Klimaeva L.1, Okina E.1, Knyazev A.2
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隶属关系:
- N.P. Ogarev National Research Mordovia State University
- Lobachevsky State University
- 期: 卷 93, 编号 1 (2023)
- 页面: 77-83
- 栏目: Articles
- URL: https://journals.rcsi.science/0044-460X/article/view/144983
- DOI: https://doi.org/10.31857/S0044460X23010092
- EDN: https://elibrary.ru/OZLORD
- ID: 144983
如何引用文章
详细
The photocatalytic properties of new representatives of the family of metal-free catalysts, 10-hydro-9-phenylacridine, 10-methyl-9-phenylacridinium chloride, and 10-phenyl-9-phenylacridinium chloride, were studied with respect to the reaction of molecular hydrogen generation in the presence of acids of different strength (HClO4, CH3SO3H, and CF3COOH) and reducing agents ([Bu4N]Cl, [Bu4N]Br, and [Bu4N]I). It was found that the strength of acids (p K a) and the nature of the reducing agent ( E 0) significantly affect the efficiency, i.e. turnover frequency (TOF), of the process under study. The amount of formed molecular hydrogen reaches its maximum in the case of the combination HClO4 and [Bu4N]I, characterized by minimal p K a and E0 values, respectively. The influence of the nature of substituents at the nitrogen atom in 9-phenylacridine on the efficiency of the molecular hydrogen production was analyzed. It was shown that the limiting stage of the process is the protonation of the formed radical.
作者简介
A. Dolganov
N.P. Ogarev National Research Mordovia State University
Email: dolganov_sasha@mail.ru
L. Klimaeva
N.P. Ogarev National Research Mordovia State University
E. Okina
N.P. Ogarev National Research Mordovia State University
A. Knyazev
Lobachevsky State University
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