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Synthesis of N-Substituted Morpholine C60-Fullerene Adducts in the Presence of LiOH and Lead(IV) Acetate
- Authors: Kinzyabaeva Z.S1, Fazletdinova Z.N1
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Affiliations:
- Institute of Petrochemistry and Catalysis, Ufa Federal Research Center of the Russian Academy of Sciences
- Issue: Vol 93, No 7 (2023)
- Pages: 995-1000
- Section: Articles
- URL: https://journals.rcsi.science/0044-460X/article/view/141594
- DOI: https://doi.org/10.31857/S0044460X23070028
- EDN: https://elibrary.ru/HFECZI
- ID: 141594
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Abstract
A N -phenyl-substituted morpholine adduct of C60 fullerene, 1,9-[4′-phenylmorpholine]-1,9-dihydro-(C60-Ih) [5,6]fullerene, was obtained for the first time with a yield of 56% in the reaction of 2-phenylaminoethanol with fullerene in the presence of LiOH and Pb(OAc)4 at room temperature for 1 h. The amino alcohol with an electron donor group (2-methylaminoethanol) in the reaction with fullerene showed a higher reactivity: the product 1,9-[4′-methylmorpholine]-1,9-dihydro-(С60-Ih)[5,6]fullerene was isolated in 68% yield. The presence of electron-withdrawing groups at the α- or β-carbon atom relative to the nitrogen atom in amino alcohols [carboxylic (2-amino-3-hydroxypropanoic acid, serine) or carbonyl (aminoacetic acid) groups] does not contribute to the reactions with fullerene under the studied conditions.
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About the authors
Z. S Kinzyabaeva
Institute of Petrochemistry and Catalysis, Ufa Federal Research Center of the Russian Academy of Sciences
Email: zefa5@rambler.ru
Z. N Fazletdinova
Institute of Petrochemistry and Catalysis, Ufa Federal Research Center of the Russian Academy of Sciences
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