Cobalt-Doped Chalcopyrites CuGaSe2: Synthesis and Magnetic Properties

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Two series of cobalt-doped CuGa1 – xCoxSe2 and Cu1 – x/2Ga1 – x/2CoxSe2 chalcopyrites were prepared. Cobalt in part entered the chalcopyrite structure to ensure the appearance of paramagnetic properties, while in part it remained involved in cobalt selenide admixtures. High-temperature quenching forced almost all of the cobalt to enter the crystal structure in the Cu1 – x/2Ga1 – x/2CoxSe2 samples. Significant ferromagnetism appears in the Cu0.9Ga0.9Co0.2Se2 sample, which had the highest cobalt concentration, in particular at room temperature.

作者简介

M. Zykin

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: mzykin@gmail.com
119991, Moscow, Russia

S. Golodukhina

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: mzykin@gmail.com
119991, Moscow, Russia

N. Efimov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

编辑信件的主要联系方式.
Email: mzykin@gmail.com
119991, Moscow, Russia

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版权所有 © М.А. Зыкин, С.В. Голодухина, Н.Н. Ефимов, 2023

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