Isomeric Molecular Forms of Pseudo-Binuclear Bismuth(III) Dithiocarbamate [Bi2{S2CN(CH2)6}6]: Preparation, Thermal Behavior, and Structural Effect of Its Solvation with DMSO, [Bi2{S2CN(CH2)6}6]⋅2(CH3)2SO
- Autores: Novikova E.1, Egorova I.2, Isakovskaya K.3,4, Ivanov A.1
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Afiliações:
- Institute of Geology and Nature Management, Far Eastern Branch, Russian Academy of Sciences
- Blagoveshchensk State Pedagogical University
- Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- Mendeleev University of Chemical Technology of Russia
- Edição: Volume 68, Nº 10 (2023)
- Páginas: 1433-1446
- Seção: КООРДИНАЦИОННЫЕ СОЕДИНЕНИЯ
- URL: https://journals.rcsi.science/0044-457X/article/view/140309
- DOI: https://doi.org/10.31857/S0044457X23600548
- EDN: https://elibrary.ru/NLZMXC
- ID: 140309
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Resumo
Bismuth(III) hexamethylenedithiocarbamate (HmDtc) [Bi2{S2CN(CH2)6}6] (I) and its solvated with dimethyl sulfoxide form [Bi2(S2CNHm)6]⋅2(CH3)2SO (II) have been obtained. The crystal structure of compound I shows an unusual alternation of two unsymmetrical isomeric pseudo-binuclear [Bi1/1B(HmDtc)3···Bi1A/1C(HmDtc)3] molecules, each of which involves two non-equivalent mononuclear moieties combined by secondary Bi···S bonds. The solvation of complex I leads to the structural unification of isomeric [Bi(HmDtc)3] molecules followed by their self-organization into centrosymmetric pseudo-dimers in the structure of compound II. All HmDtc ligands coordinate in S,S'-anisobidentate mode to form four isomeric (in I) or structurally unique [Bi(HmDtc)3] molecules (in II), whose distorted polyhedra can be approximated by pentagonal pyramid or octahedron. Solvating DMSO molecules are retained in the structure II by C–H···O hydrogen bonds. The analysis of energy dispersive X-ray spectra allowed one to identify the residual matter obtained by thermolysis of the complexes as Bi2S3 with admixture of Bi0.
Sobre autores
E. Novikova
Institute of Geology and Nature Management, Far Eastern Branch, Russian Academy of Sciences
Email: alexander.v.ivanov@chemist.com
675000, Blagoveshchensk, Russia
I. Egorova
Blagoveshchensk State Pedagogical University
Email: alexander.v.ivanov@chemist.com
675000, Blagoveshchensk, Russia
K. Isakovskaya
Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; Mendeleev University of Chemical Technology of Russia
Email: alexander.v.ivanov@chemist.com
119991, Moscow, Russia; 125047, Moscow, Russia
A. Ivanov
Institute of Geology and Nature Management, Far Eastern Branch, Russian Academy of Sciences
Autor responsável pela correspondência
Email: alexander.v.ivanov@chemist.com
675000, Blagoveshchensk, Russia
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