Structure of the Local Environment and Hyperfine Interactions of 57Fe Probe Nuclei in AMnO3 (A = Sc, In)
- Authors: Sobolev A.V.1, Šandalova S.1, Smirnova M.N.2, Belik A.A.3, Glazkova Y.S.1, Presniakov I.A.1,4
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Affiliations:
- Moscow State University
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS)
- Shenzhen MSU-BIT University
- Issue: Vol 68, No 10 (2023)
- Pages: 1364-1372
- Section: СИНТЕЗ И СВОЙСТВА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
- URL: https://journals.rcsi.science/0044-457X/article/view/140301
- DOI: https://doi.org/10.31857/S0044457X23600779
- EDN: https://elibrary.ru/EWUTKV
- ID: 140301
Cite item
Abstract
The results of a Mössbauer study of hyperfine interactions of 57Fe probe nuclei in isostructural hexagonal manganites h-ScMnO3 and h-InMnO3 are presented. The results of measurements of the Mössbauer spectra at T > TN, as well as calculations of the parameters of the electric field gradient tensor at 57Fe nuclei, demonstrated different behavior of the probe iron ions in these isostructural systems, reflecting the difference in the processes of defect formation in their crystal lattices. On the contrary, measurements at T < TN did not reveal any differences in the local magnetic structure of 57Fe probe atoms in these oxides.
About the authors
A. V. Sobolev
Moscow State University
Email: janglaz@bk.ru
199991, Moscow, Russia
S. Šandalova
Moscow State University
Email: janglaz@bk.ru
199991, Moscow, Russia
M. N. Smirnova
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: janglaz@bk.ru
199991, Moscow, Russia
A. A. Belik
Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS)
Email: janglaz@bk.ru
Namiki, 1-1, Tsukuba, 305-0044, Ibaraki, Japan
Ya. S. Glazkova
Moscow State University
Email: janglaz@bk.ru
199991, Moscow, Russia
I. A. Presniakov
Moscow State University; Shenzhen MSU-BIT University
Author for correspondence.
Email: janglaz@bk.ru
199991, Moscow, Russia; 518115, Shenzhen, China
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