Structure of the Local Environment and Hyperfine Interactions of  57 Fe Probe Nuclei in AMnO 3  (A = Sc, In)

A. V. Sobolev; Соболев А. В.; S. Šandalova; Шандалова С.; M. N. Smirnova; Смирнова М. Н.; A. A. Belik; Белик А. А.; Ya. S. Glazkova; Глазкова Я. С.; I. A. Presniakov; Пресняков И. А.

doi:10.31857/S0044457X23600779

Structure of the Local Environment and Hyperfine Interactions of ⁵⁷Fe Probe Nuclei in AMnO₃ (A = Sc, In)

Authors: Sobolev A.V.¹, Šandalova S.¹, Smirnova M.N.², Belik A.A.³, Glazkova Y.S.¹, Presniakov I.A.¹^,4
Affiliations:
1. Moscow State University
2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
3. Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS)
4. Shenzhen MSU-BIT University
Issue: Vol 68, No 10 (2023)
Pages: 1364-1372
Section: СИНТЕЗ И СВОЙСТВА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
URL: https://journals.rcsi.science/0044-457X/article/view/140301
DOI: https://doi.org/10.31857/S0044457X23600779
EDN: https://elibrary.ru/EWUTKV
ID: 140301

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Abstract
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Abstract

The results of a Mössbauer study of hyperfine interactions of 57Fe probe nuclei in isostructural hexagonal manganites h-ScMnO3 and h-InMnO3 are presented. The results of measurements of the Mössbauer spectra at T > TN, as well as calculations of the parameters of the electric field gradient tensor at 57Fe nuclei, demonstrated different behavior of the probe iron ions in these isostructural systems, reflecting the difference in the processes of defect formation in their crystal lattices. On the contrary, measurements at T < TN did not reveal any differences in the local magnetic structure of 57Fe probe atoms in these oxides.

Keywords

hexagonal manganites, Mössbauer spectroscopy, ⁵⁷Fe probe atoms, antistructure defects

References

Koehler W.C., Yakel H.L., Wollan E.O. et al. // Phys. Lett. 1964. V. 9. P. 93. https://doi.org/10.1016/0031-9163(64)90089-7
Wood V.E., Austin A.E., Collings E.W. et al. // Phys. Chem. Solids. 1973. V. 34. P. 859. https://doi.org/10.1016/S0022-3697(73)80088-5
Fiebig M., Frohlich D., Lottermoser T. et al. // Phys. Rev. B. 2002. V. 65. P. 224421. https://doi.org/10.1103/PhysRevB.65.224421
Munoz A., Alonso J.A., Matinez-Lope M.J. et al. // Phys. Rew. B. 2000. V. 62. P. 9498. https://doi.org/10.1103/PhysRevB.62.9498
Lorenz B. // ISRN. Condens. Matter Phys. 2013. V. 2013. P. 497073. https://doi.org/10.1155/2013/497073
Uusi-Esko K. Synthesis and Characterization of Ternary Manganese Oxides. Diss. for the degree of Doctor of Science in Technology. Aalto University Press, Helsinki, 2011.
Uusi-Esko K., Malm J., Imamura N. et al. // M. Mater. Chem. Phys. 2008. V. 112. P. 1029. https://doi.org/10.1016/j.matchemphys.2008.07.009
Yakel H.L., Koehler W.C., Bertaut E.F. et al. // Acta Crystallogr. 1963. V. 16. P. 957. https://doi.org/10.1107/S0365110X63002589
Fedorova O.M., Balakirev V.F., Golikov Y.V. // Russ. J. Inorg. Chem. 2011. V. 56. P. 173. https://doi.org/10.1134/S0036023611020070
Gilleo. M.A. // Acta Crystallogr. 1957. V. 10. P. 161. https://doi.org/10.1107/S0365110X57000535
Yakel. H.L. // Acta Crystallogr. 1955. V. 8. P. 394. https://doi.org/10.1107/S0365110X55001291
Belik A.A., Kamba S., Savinov M. et al. // Phys. Rev. B. 2009. V. 79. P. 054411. https://doi.org/10.1103/PhysRevB.79.054411
Greedan J.E., Bieringer M., Britten J.F. et al. // J. Solid State Chem. 1995. V. 116. P. 118. https://doi.org/10.1006/jssc.1995.1192
Fabrèges X., Mirebeau I., Petit S. et al. // Phys. Rev. B. 2011. V. 84. P. 054455. https://doi.org/10.1103/PhysRevB.84.054455
Yi W., Presniakov I.A., Sobolev A.V. et al. // Sci. Technol. Adv. Mater. 2015. V. 16. P. 024801. https://doi.org/10.1088/1468-6996/16/2/024801
Glazkova I.S., Sobolev A.V., Yi W. et al. // J. Exp. Theor. Phys. 2018. V. 126. P. 514. https://doi.org/10.1134/S1063776118030135
Glazkova I.S., Smirnova M.N., Kondrat’eva O.N. et al. // Russ. J. Inorg. Chem. 2023. V. 68. https://doi.org/10.1134/S0036023623600387
Тетерин Ю.А., Смирнова М.Н., Маслаков К.И. и др. // Журн. неорган. химии. 2023. Т. 68. № 7. С. 904. https://doi.org/10.31857/S0044457X23600135
Chen H., Yu T., Gao P. // Inorg. Chem. 2013. V. 52. P. 9692. https://doi.org/10.1021/ic4016838
Petricek V., Dusek M., Palatinus L. // Z. Crystallogr. 2014. V. 229. P. 345. https://doi.org/10.1515/zkri-2014-1737
Cockayne E., Levin I., Wu H. et al. // Phys. Rev. B. 2013. V. 87. P. 184413. https://doi.org/10.1103/PhysRevB.87.184413
Bekheet M.F., Svoboda I., Liu N. et al. // J. Solid State Chem. 2016. V. 241. P. 54. https://doi.org/10.1016/j.jssc.2016.05.031
Sobolev A.V., Akulenko A.A., Glazkova I.S. et al. // J. Phys. Chem. C. 2018. V. 122. P. 19767. https://doi.org/10.1021/acs.jpcc.8b05516
Matsnev M.E., Rusakov V.S. // AIP Conf. Proc. 2012. V. 1489. P. 178. https://doi.org/10.1063/1.4759488
Menil F. // J. Phys. Chem. Solids. 1985. V. 46. P. 763. https://doi.org/10.1016/0022-3697(85)90001-0
Presniakov I.A., Rusakov V.S., Gubaidulina T.V. et al. // Phys. Rev. B. 2007. V. 76. P. 214407. https://doi.org/10.1103/PhysRevB.76.214407
Glazkova Y.S., Terada N., Matsushita Y. et al. // Inorg. Chem. 2015. V. 54. P. 9081. https://doi.org/10.1021/acs.inorgchem.5b01472
Kim S.J., Demazeau G., Presnyakov I.A. et al. // Russ. J. Inorg. Chem. 2003. V. 48. P. 1394.
Presnyakov I.A., Rusakov V.S., Sobolev A.V. et al. // Russ. J. Inorg. Chem. 2009. V. 54. P. 1957. https://doi.org/10.1134/S0036023609120195
Belik A.A., Matsushita Y., Tanaka M. et al. // Angew. Chem. Int. Ed. 2010. V. 49. P. 7723. https://doi.org/10.1002/anie.201003080
Shannon R.D., Fischer R.X. // Phys. Rev. B. 2006. V. 73. P. 235111. https://doi.org/10.1103/PhysRevB.73.235111
Sobolev A.V., Kozlyakova E.S., Glazkova I.S. et al. // J. Phys. Chem. C. 2018. V. 122. P. 19746. https://doi.org/10.1021/acs.jpcc.8b05122
Azuma M., Takata K., Saito T. et al. // J. Am. Chem. Soc. 2005. V. 127. P. 8889. https://doi.org/10.1021/ja0512576
Yi W., Princep A.J., Guo Y. et al. // Inorg. Chem. 2015. V. 54. P. 8012. https://doi.org/10.1021/acs.inorgchem.5b01195
Yamada I., Murakami M., Hayashi N. et al. // Inorg. Chem. 2016. V. 55. P. 1715. https://doi.org/10.1021/acs.inorgchem.5b02623