Nucleophilic Addition of Aliphatic Diamines NH2(CH2)nNH2 (n = 6, 9) to Nitrilium Derivatives of the closo-Decaborate Anion [2-B10H9NCR]– (R = CH3, C2H5, nC3H7)
- Authors: Voinova V.V.1, Selivanov N.A.1, Bykov A.Y.1, Klyukin I.N.1, Zhdanov A.P.1, Zhizhin K.Y.1, Kuznetsov N.T.1
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Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- Issue: Vol 68, No 10 (2023)
- Pages: 1358-1363
- Section: СИНТЕЗ И СВОЙСТВА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
- URL: https://journals.rcsi.science/0044-457X/article/view/140300
- DOI: https://doi.org/10.31857/S0044457X23600883
- EDN: https://elibrary.ru/LNEGCS
- ID: 140300
Cite item
Abstract
The reaction of a number of nitrilium derivatives of the closo-decaborate anion with hexamethylene- and nonamethylenediamine has been studied. It has been shown that the process proceeds with the functionalization of both amino groups of the nucleophile to form amidines of the type (Bu4N)2[B10H9NH=C(R)NH (CH2)nNH(R)C=NHB10H9] (R = CH3, C2H5, nC3H7; n = 6, 9). Target compounds have been characterized by high resolution multinuclear NMR and ESI mass spectrometry.
About the authors
V. V. Voinova
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: zhdanov@igic.ras.ru
119991, Moscow, Russia
N. A. Selivanov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: zhdanov@igic.ras.ru
119991, Moscow, Russia
A. Yu. Bykov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: zhdanov@igic.ras.ru
119991, Moscow, Russia
I. N. Klyukin
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: zhdanov@igic.ras.ru
Россия, 119991, Москва,
Ленинский пр-т, 31
A. P. Zhdanov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: zhdanov@igic.ras.ru
119991, Moscow, Russia
K. Yu. Zhizhin
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: zhdanov@igic.ras.ru
119991, Moscow, Russia
N. T. Kuznetsov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: zhdanov@igic.ras.ru
119991, Moscow, Russia
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