Synthesis and Structures of Cobalt(II) Coordination Compounds with Isomeric Forms of Octadecahydroeicosaborate Anion

V. V. Avdeeva; Авдеева В. В.; A. S. Kubasov; Кубасов А. С.; A. V. Golubev; Голубев А. В.; S. E. Nikiforova; Никифорова С. Е.; E. A. Malinina; Малинина Е. А.; N. T. Kuznetsov; Кузнецов Н. Т.

doi:10.31857/S0044457X2360086X

Synthesis and Structures of Cobalt(II) Coordination Compounds with Isomeric Forms of Octadecahydroeicosaborate Anion

Authors: Avdeeva V.V.¹, Kubasov A.S.¹, Golubev A.V.¹, Nikiforova S.E.¹, Malinina E.A.¹, Kuznetsov N.T.¹
Affiliations:
1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Issue: Vol 68, No 9 (2023)
Pages: 1235-1243
Section: КООРДИНАЦИОННЫЕ СОЕДИНЕНИЯ
URL: https://journals.rcsi.science/0044-457X/article/view/136487
DOI: https://doi.org/10.31857/S0044457X2360086X
EDN: https://elibrary.ru/WKBGSE
ID: 136487

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Abstract
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Abstract

Coordination compounds [Co(DMF)6][B20H18] containing isomeric forms of the macropolyhedral cluster [trans-B20H18]2– and [iso-B20H18]2– have been synthesized. Complex [Co(DMF)6][trans-B20H18] has been prepared by the reaction of a salt of the boron cluster anion with cobalt(II) chloride in dimethylformamide; complex [Co(DMF)6][iso-B20H18] has been isolated when recrystallized from water during spontaneous isomerization of the macropolyhedral cluster. The coordination compounds have been identified by IR spectroscopy, 11B NMR spectroscopy, and X-ray diffraction analysis.

Keywords

boron cluster anions, UV irradiation, isomerization, octadecahydroeicosaborate anion

References

Chamberland B.L., Muetterties E.L. // Inorg. Chem. 1964. V. 3. P. 1450. https://doi.org/10.1021/ic50020a025
Hawthorne M.F., Pilling R.L. // J. Am. Chem. Soc. 1966. V. 88. P. 3873. https://doi.org/10.1021/ja00968a044
Hawthorne M.F., Shelly K., Li F. // Chem. Commun. 2002. P. 547. https://doi.org/10.1039/B110076A
Curtis Z.B., Young C., Dickerson R., Kaczmarczyk A. // Inorg. Chem. 1974. V. 13. P. 1760. https://doi.org/10.1021/ic50137a046
Voinova V.V., Klyukin I.N., Novikov A.S. et al. // Russ. J. Inorg. Chem. 2021. V. 66. P. 295. https://doi.org/10.1134/S0036023621030190
Francés-Monerris A., Holub J., Roca-Sanjuán D. et al. // Phys. Chem. Lett. 2019. V. 10. P. 6202. https://doi.org/10.1021/acs.jpclett.9b02290
Kaczmarczyk A., Dobrott R.D., Lipscomb W.N. // Proc. Nat. Acad. Sci. USA. 1962. V. 48. P. 729.
Hawthorne M.F., Pilling R.L., Stokely P.F., Garrett P.M. // J. Am. Chem. Soc. 1963. V. 85. P. 3704.
Li F., Shelly K., Knobler C.B., Hawthorne M.F. // Angew. Chem. Int. Ed. 1998. V. 37. P. 1868. https://doi.org/10.1002/(SICI)1521-3773(19980803)37: 13/14<1868::AID-ANIE1868>3.0.CO;2-Z
Avdeeva V.V., Buzin M.I., Dmitrienko A.O. et al. // Chem. Eur. J. 2017. V. 23. P. 16819. https://doi.org/10.1002/chem.201703285
Avdeeva V.V., Malinina E.A., Zhizhin K.Y. et al. // J. Struct. Chem. 2019. V. 60. P. 692. https://doi.org/10.1134/S0022476619050020
Avdeeva V.V., Malinina E.A., Kuznetsov N.T. // Russ. J. Inorg. Chem. 2020. V. 65. P. 335. https://doi.org/10.1134/S003602362003002X
Avdeeva V.V., Buzin M.I., Malinina E.A. et al. // Cryst. Eng. Comm. 2015. V. 17. P. 8870. https://doi.org/10.1039/C5CE00859J
Bernhardt E., Brauer D.J., Finze M., Willner H. // Angew. Chem. Int. Ed. 2007. V. 46. P. 2927.
Avdeeva V.V., Kubasov A.S., Korolenko S.E. et al. // Russ. J. Inorg. Chem. 2022. V. 67. P. 1169. https://doi.org/10.1134/S0036023622080022
Il’inchik E.A., Polyanskaya T.M., Drozdova M.K. et al. // Russ. J. Gen. Chem. 2005. V. 75. P. 1545. https://doi.org/10.1007/s11176-005-0464-y
Avdeeva V.V., Kubasov A.S., Korolenko S.E. et al. // Polyhedron. 2022. V. 217. P. 115740. https://doi.org/10.1016/j.poly.2022.115740
Miller H.C., Miller N.E., Muetterties E.L. // J. Am. Chem. Soc. 1963. V. 85. P. 3885.
APEX2 (V. 2009, 5-1), SAINT (V7.60A), SADABS (2008/1). Bruker AXS Inc., Madison, Wisconsin, USA, 2008-2009.
Sheldrick G.M. // Acta Crystallogr., Sect. C: Struct. Chem. 2015. V. 71. P. 3. https://doi.org/10.1107/S2053229614024218
Dolomanov O.V., Bourhis L.J., Gildea R.J. et al. // J. Appl. Crystallogr. 2009. V. 42. P. 339. https://doi.org/10.1107/S0021889808042726
Neese F. // Wiley Interdiscip. Rev. Comput. Mol. Sci. 2018. V. 8. P. 1. https://doi.org/10.1002/wcms.1327
Neese F. // Wiley Interdiscip. Rev. Comput. Mol. Sci. 2012. V. 2. P. 73. https://doi.org/10.1002/wcms.81
Chemcraft — graphical software for visualization of quantum chemistry computations. Version 1.8, build 648. https://www.chemcraftprog.com
Авдеева В.В., Кубасов А.С., Никифорова С.Е. и др. // Коорд. химия. 2023. Т. 49. № 6. С. 1. https://doi.org/10.31857/S0132344X22600576
Avdeeva V.V., Privalov V.I., Kubasov A.S. et al. // Inorg. Chim. Acta. 2023. V. 555. P. 121564. https://doi.org/10.1016/j.ica.2023.121564
Uflyand I.E., Tkachev V.V., Zhinzhilo V.A., Dzhardimalieva G.I. // J. Coord. Chem. 2021. V. 74. P. 649. https://doi.org/10.1080/00958972.2021.1881067
Eissmann F., Böhle T., Mertens F.O.R.L., Weber E. // Acta Crystallogr., Sect. E. 2010. V. 66. P. m279. https://doi.org/10.1107/S160053681000454X
Khutornoi V.A., Naumov N.G., Mironov Yu.V. et al. // Russ. J. Coord. Chem. 2002. V. 28. P. 183. https://doi.org/10.1023/A:1014724002211
Yaqin Guo, Xiuli Wang, Yangguang Li et al. // J. Coord. Chem. 2004. V. 57. P. 445. https://doi.org/10.1080/00958970410001671084
Shmakova A.A., Akhmetova M.M., Volchek V.V. et al. // New J. Chem. 2018. V. 42. P. 7940. https://doi.org/10.1039/C7NJ04702A
Avdeeva V.V., Vologzhanina A.V., Ugolkova E.A. et al. // J. Solid State Chem. 2021. V. 296. P. 121989. https://doi.org/10.1016/j.jssc.2021.121989
DeBoer B.G., Zalkin A., Templeton D.H. // Inorg. Chem. 1968. V. 7. P. 1085. https://doi.org/10.1021/ic50064a008
Montalvo S.J., Todd W.H., Feakes D.A. // J. Organomet. Chem. 2015. V. 798. P. 141. https://doi.org/10.1016/j.jorganchem.2015.05.064
Truong N.X., Jaeger B.A., Gewinner S. et al. // J. Phys. Chem. C. 2017. V. 121. P. 9560. https://doi.org/10.1021/acs.jpcc.7b01290
Shixiong Li, Zhengping Zhang, Zhengwen Long et al. // Sci. Rep. 2016. V. 6. P. 25020. https://doi.org/10.1038/srep25020
Biliskov N. // Infrared Spectroscopy: Theory, Advances and Development / Ed. Cozzolino D. Nova Science Publishers, 2014. https://doi.org/10.13140/2.1.3420.7687
Kubasov A.S., Golubev A.V., Bykov A.Yu. et al. // J. Mol. Struct. 2021. V. 1241. P. 130591. https://doi.org/10.1016/j.molstruc.2021.130591
Palumbo O., Nguyen P., Jensen C.M., Paolone A. // Int. J. Hydrogen Energy. 2016. V. 14. P. 5986. https://doi.org/10.1016/j.ijhydene.2016.02.124
Malinina E.A., Myshletsov I.I., Buzanov G.A. et al. // Molecules. 2023. V. 28. P. 453. https://doi.org/10.3390/molecules28010453
Авдеева В.В., Полякова И.Н., Вологжанина А.В. и др. // Журн. неорган. химии. 2016. Т. 61. № 9. С. 1182.
Малинина Е.А., Гоева Л.В., Бузанов Г.А. и др. // Журн. неорган. химии. 2020. Т. 65. № 1. С. 124.
Малинина Е.А., Гоева Л.В., Бузанов Г.А. и др. // Журн. неорган. химии. 2019. Т. 64. № 11. С. 1136.
Петричко М.И., Караваев И.А., Савинкина Е.В. и др. // Журн. неорган. химии. 2023. Т. 68. № 4. С. 482. https://doi.org/10.31857/S0044457X22601821