Synthesis and Structures of Cobalt(II) Coordination Compounds with Isomeric Forms of Octadecahydroeicosaborate Anion

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

Coordination compounds [Co(DMF)6][B20H18] containing isomeric forms of the macropolyhedral cluster [trans-B20H18]2– and [iso-B20H18]2– have been synthesized. Complex [Co(DMF)6][trans-B20H18] has been prepared by the reaction of a salt of the boron cluster anion with cobalt(II) chloride in dimethylformamide; complex [Co(DMF)6][iso-B20H18] has been isolated when recrystallized from water during spontaneous isomerization of the macropolyhedral cluster. The coordination compounds have been identified by IR spectroscopy, 11B NMR spectroscopy, and X-ray diffraction analysis.

About the authors

V. V. Avdeeva

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: avdeeva.varvara@mail.ru
119991, Moscow, Russia

A. S. Kubasov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: avdeeva.varvara@mail.ru
119991, Moscow, Russia

A. V. Golubev

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: avdeeva.varvara@mail.ru
119991, Moscow, Russia

S. E. Nikiforova

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: avdeeva.varvara@mail.ru
119991, Moscow, Russia

E. A. Malinina

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: avdeeva.varvara@mail.ru
119991, Moscow, Russia

N. T. Kuznetsov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Author for correspondence.
Email: avdeeva.varvara@mail.ru
119991, Moscow, Russia

References

  1. Chamberland B.L., Muetterties E.L. // Inorg. Chem. 1964. V. 3. P. 1450. https://doi.org/10.1021/ic50020a025
  2. Hawthorne M.F., Pilling R.L. // J. Am. Chem. Soc. 1966. V. 88. P. 3873. https://doi.org/10.1021/ja00968a044
  3. Hawthorne M.F., Shelly K., Li F. // Chem. Commun. 2002. P. 547. https://doi.org/10.1039/B110076A
  4. Curtis Z.B., Young C., Dickerson R., Kaczmarczyk A. // Inorg. Chem. 1974. V. 13. P. 1760. https://doi.org/10.1021/ic50137a046
  5. Voinova V.V., Klyukin I.N., Novikov A.S. et al. // Russ. J. Inorg. Chem. 2021. V. 66. P. 295. https://doi.org/10.1134/S0036023621030190
  6. Francés-Monerris A., Holub J., Roca-Sanjuán D. et al. // Phys. Chem. Lett. 2019. V. 10. P. 6202. https://doi.org/10.1021/acs.jpclett.9b02290
  7. Kaczmarczyk A., Dobrott R.D., Lipscomb W.N. // Proc. Nat. Acad. Sci. USA. 1962. V. 48. P. 729.
  8. Hawthorne M.F., Pilling R.L., Stokely P.F., Garrett P.M. // J. Am. Chem. Soc. 1963. V. 85. P. 3704.
  9. Li F., Shelly K., Knobler C.B., Hawthorne M.F. // Angew. Chem. Int. Ed. 1998. V. 37. P. 1868. https://doi.org/10.1002/(SICI)1521-3773(19980803)37: 13/14<1868::AID-ANIE1868>3.0.CO;2-Z
  10. Avdeeva V.V., Buzin M.I., Dmitrienko A.O. et al. // Chem. Eur. J. 2017. V. 23. P. 16819. https://doi.org/10.1002/chem.201703285
  11. Avdeeva V.V., Malinina E.A., Zhizhin K.Y. et al. // J. Struct. Chem. 2019. V. 60. P. 692. https://doi.org/10.1134/S0022476619050020
  12. Avdeeva V.V., Malinina E.A., Kuznetsov N.T. // Russ. J. Inorg. Chem. 2020. V. 65. P. 335. https://doi.org/10.1134/S003602362003002X
  13. Avdeeva V.V., Buzin M.I., Malinina E.A. et al. // Cryst. Eng. Comm. 2015. V. 17. P. 8870. https://doi.org/10.1039/C5CE00859J
  14. Bernhardt E., Brauer D.J., Finze M., Willner H. // Angew. Chem. Int. Ed. 2007. V. 46. P. 2927.
  15. Avdeeva V.V., Kubasov A.S., Korolenko S.E. et al. // Russ. J. Inorg. Chem. 2022. V. 67. P. 1169. https://doi.org/10.1134/S0036023622080022
  16. Il’inchik E.A., Polyanskaya T.M., Drozdova M.K. et al. // Russ. J. Gen. Chem. 2005. V. 75. P. 1545. https://doi.org/10.1007/s11176-005-0464-y
  17. Avdeeva V.V., Kubasov A.S., Korolenko S.E. et al. // Polyhedron. 2022. V. 217. P. 115740. https://doi.org/10.1016/j.poly.2022.115740
  18. Miller H.C., Miller N.E., Muetterties E.L. // J. Am. Chem. Soc. 1963. V. 85. P. 3885.
  19. APEX2 (V. 2009, 5-1), SAINT (V7.60A), SADABS (2008/1). Bruker AXS Inc., Madison, Wisconsin, USA, 2008-2009.
  20. Sheldrick G.M. // Acta Crystallogr., Sect. C: Struct. Chem. 2015. V. 71. P. 3. https://doi.org/10.1107/S2053229614024218
  21. Dolomanov O.V., Bourhis L.J., Gildea R.J. et al. // J. Appl. Crystallogr. 2009. V. 42. P. 339. https://doi.org/10.1107/S0021889808042726
  22. Neese F. // Wiley Interdiscip. Rev. Comput. Mol. Sci. 2018. V. 8. P. 1. https://doi.org/10.1002/wcms.1327
  23. Neese F. // Wiley Interdiscip. Rev. Comput. Mol. Sci. 2012. V. 2. P. 73. https://doi.org/10.1002/wcms.81
  24. Chemcraft — graphical software for visualization of quantum chemistry computations. Version 1.8, build 648. https://www.chemcraftprog.com
  25. Авдеева В.В., Кубасов А.С., Никифорова С.Е. и др. // Коорд. химия. 2023. Т. 49. № 6. С. 1. https://doi.org/10.31857/S0132344X22600576
  26. Avdeeva V.V., Privalov V.I., Kubasov A.S. et al. // Inorg. Chim. Acta. 2023. V. 555. P. 121564. https://doi.org/10.1016/j.ica.2023.121564
  27. Uflyand I.E., Tkachev V.V., Zhinzhilo V.A., Dzhardimalieva G.I. // J. Coord. Chem. 2021. V. 74. P. 649. https://doi.org/10.1080/00958972.2021.1881067
  28. Eissmann F., Böhle T., Mertens F.O.R.L., Weber E. // Acta Crystallogr., Sect. E. 2010. V. 66. P. m279. https://doi.org/10.1107/S160053681000454X
  29. Khutornoi V.A., Naumov N.G., Mironov Yu.V. et al. // Russ. J. Coord. Chem. 2002. V. 28. P. 183. https://doi.org/10.1023/A:1014724002211
  30. Yaqin Guo, Xiuli Wang, Yangguang Li et al. // J. Coord. Chem. 2004. V. 57. P. 445. https://doi.org/10.1080/00958970410001671084
  31. Shmakova A.A., Akhmetova M.M., Volchek V.V. et al. // New J. Chem. 2018. V. 42. P. 7940. https://doi.org/10.1039/C7NJ04702A
  32. Avdeeva V.V., Vologzhanina A.V., Ugolkova E.A. et al. // J. Solid State Chem. 2021. V. 296. P. 121989. https://doi.org/10.1016/j.jssc.2021.121989
  33. DeBoer B.G., Zalkin A., Templeton D.H. // Inorg. Chem. 1968. V. 7. P. 1085. https://doi.org/10.1021/ic50064a008
  34. Montalvo S.J., Todd W.H., Feakes D.A. // J. Organomet. Chem. 2015. V. 798. P. 141. https://doi.org/10.1016/j.jorganchem.2015.05.064
  35. Truong N.X., Jaeger B.A., Gewinner S. et al. // J. Phys. Chem. C. 2017. V. 121. P. 9560. https://doi.org/10.1021/acs.jpcc.7b01290
  36. Shixiong Li, Zhengping Zhang, Zhengwen Long et al. // Sci. Rep. 2016. V. 6. P. 25020. https://doi.org/10.1038/srep25020
  37. Biliskov N. // Infrared Spectroscopy: Theory, Advances and Development / Ed. Cozzolino D. Nova Science Publishers, 2014. https://doi.org/10.13140/2.1.3420.7687
  38. Kubasov A.S., Golubev A.V., Bykov A.Yu. et al. // J. Mol. Struct. 2021. V. 1241. P. 130591. https://doi.org/10.1016/j.molstruc.2021.130591
  39. Palumbo O., Nguyen P., Jensen C.M., Paolone A. // Int. J. Hydrogen Energy. 2016. V. 14. P. 5986. https://doi.org/10.1016/j.ijhydene.2016.02.124
  40. Malinina E.A., Myshletsov I.I., Buzanov G.A. et al. // Molecules. 2023. V. 28. P. 453. https://doi.org/10.3390/molecules28010453
  41. Авдеева В.В., Полякова И.Н., Вологжанина А.В. и др. // Журн. неорган. химии. 2016. Т. 61. № 9. С. 1182.
  42. Малинина Е.А., Гоева Л.В., Бузанов Г.А. и др. // Журн. неорган. химии. 2020. Т. 65. № 1. С. 124.
  43. Малинина Е.А., Гоева Л.В., Бузанов Г.А. и др. // Журн. неорган. химии. 2019. Т. 64. № 11. С. 1136.
  44. Петричко М.И., Караваев И.А., Савинкина Е.В. и др. // Журн. неорган. химии. 2023. Т. 68. № 4. С. 482. https://doi.org/10.31857/S0044457X22601821

Supplementary files

Supplementary Files
Action
1. JATS XML
2.

Download (777KB)
3.

Download (66KB)
4.

Download (94KB)
5.

Download (53KB)
6.

Download (348KB)
7.

Download (677KB)
8.

Download (366KB)

Copyright (c) 2023 В.В. Авдеева, А.С. Кубасов, А.В. Голубев, С.Е. Никифорова, Е.А. Малинина, Н.Т. Кузнецов

This website uses cookies

You consent to our cookies if you continue to use our website.

About Cookies