SYNTHESIS OF g-C3N4 USING POLYMERIZED TRITHIOCYANURIC ACID: EFFECT OF POLYMERIZATION DEGREE ON STRUCTURE AND PHOTOCATALYTIC PROPERTIES

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Abstract

This study investigates the use of polymerized trithiocyanuric acid (pTTCA) with varying degrees of polymerization (0–100%) as a precursor for the synthesis of graphitic carbon nitride (g-C3N4). The influence of pTTCA polymerization degree on the structural, morphological, and photocatalytic properties of the resulting material is examined. Particular attention is given to changes in chemical composition, including doping with sulfur, oxygen, and cyano groups, as well as morphological transformations from porous to denser structures. The experiments demonstrate that the use of pTTCA enables effective control over the physicochemical properties of g-C3N4, enhancing its photocatalytic activity in the degradation of organic pollutants.

About the authors

M. D Lebedev

Ivanovo State University of Chemistry and Technology

Ivanovo, Russia

A. A Goncharenko

Ivanovo State University of Chemistry and Technology

Ivanovo, Russia

I. A Skvortsov

Ivanovo State University of Chemistry and Technology

Ivanovo, Russia

A. S Vashurin

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: vashurin@igic.ras.ru
Moscow, Russia

References

  1. Kurenkova A.Yu., Saraev A.A., Alekseev R.F. et al. // Inorg. Chem. Commun. 2025. V. 173. P. 113863. https://doi.org/10.1016/j.inoche.2024.113863
  2. Zhurenok A.V., Kurenkova A.Yu., Zazulya A.E. et al. // Russ. Chem. Bull. 2025. V. 74. № 3. P. 733. https://doi.org/10.1007/s11172-025-4566-x
  3. Johnson E., Raj A., Kottarathil S. et al. // Sep. Purif. Technol. 2025. V. 364. P. 132521. https://doi.org/10.1016/j.seppur.2025.132521
  4. Zhurenok A.V., Markovskaya D.V., Lomakina V.A. et al. // Kinet. Catal. 2024. V. 65. № 6. P. 649. https://doi.org/10.1134/S0023158424602390
  5. Sheik Moideen Thaha S.K., Hasini M.P., Nair R.R. et al. // Mater. Sci. Eng., B. 2025. V. 320. P. 118408. https://doi.org/10.1016/j.mseb.2025.118408
  6. Xu C., Li Q., Dong P. et al. // J. Solid State Chem. 2025. V. 345. P. 125248. https://doi.org/10.1016/j.jssc.2025.125248
  7. Wang J., Wang S. // Coord. Chem. Rev. 2022. V. 453. P. 214338. https://doi.org/10.1016/j.ccr.2021.214338
  8. Liu X., Xu X., Gan H. et al. // Catalysts. 2023. V. 13. № 5. P. 848. https://doi.org/10.3390/catal13050848
  9. Козлов Д.А., Артамонов К.А., Ревенко А.О. и др. // Журн. неорган. химии. 2022. T. 67. № 5. C. 646. https://doi.org/10.31857/S00444457X22050105
  10. Чебаненко М.И., Захарова (Екимова) Н.В., Попков В.И. // Журн. прикл. химии. 2020. T. 93. № 4. C. 490. https://doi.org/10.31857/S00444461820040039
  11. Yurova V.Yu., Potapenko K.O., Aliev T.A. et al. // Int. J. Hydrogen Energy. 2024. V. 81. P. 193. https://doi.org/10.1016/j.ijhydene.2024.07.245
  12. Nabeel M.I., Hussain D., Ahmad N. et al. // Carbon. 2025. V. 243. P. 120472. https://doi.org/10.1016/j.carbon.2025.120472
  13. Чубенко Е.Б., Баглов А.В., Федотова Ю.А. и др. // Неорган. материалы. 2021. T. 57. № 2. C. 144. https://doi.org/10.31857/S0002337X21020056
  14. Чубенко Е.Б., Баглов А.В., Дудчик (Назарчук) Н.В. и др. // Кинетика и катализ. 2022. T. 63. № 2. C. 187. https://doi.org/10.31857/S0453881122020010
  15. Jiang Y., Qu F., Tian L. et al. // Appl. Surf. Sci. 2019. V. 487. P. 59. https://doi.org/10.1016/j.apsusc.2019.05.056
  16. Chen J., Hong Z., Chen Y. et al. // Mater. Lett. 2015. V. 145. P. 129. https://doi.org/10.1016/j.matlet.2015.01.073
  17. Kharatzadeh E., Khademalrasool M. // Ceram. Int. 2024. V. 50. N. 9. P. 16540. https://doi.org/10.1016/j.ceramint.2024.02.144
  18. Wang K., Li Q., Liu B. et al. // Appl. Catal. B. 2015. V. 176-177. P. 44. https://doi.org/10.1016/j.apcatb.2015.03.045
  19. Zhan J., Zhang Y., Zhang X. et al. // Colloids Surf., A. 2023. V. 663. P. 131053. https://doi.org/10.1016/j.colsurfa.2023.131053
  20. Gu Y., Li Y., Feng H. et al. // Nano. Res. 2024. V. 17. N. 6. P. 4961. https://doi.org/10.1007/s12274-024-6501-0
  21. Ермакова Е.Н., Максимовский Е.А., Юшина И.В. и др. // Журн. неорган. химии. 2023. Т. 68. № 2. С. 256. https://doi.org/10.31857/S0044457X22601547
  22. Bai X., Xing J., Huang X. et al. // Chem. Eng. J. 2025. V. 513. P. 162782. https://doi.org/10.1016/j.cej.2025.162782
  23. Li R., Cui X., Bi J. et al. // RSC Adv. 2021. V. 11. N. 38. P. 23459. https://doi.org/10.1039/D1RA03524J
  24. Wang Z., Wang J., Iqbal W. et al. // J. Phys. Chem. Solids. 2023. V. 173. P. 111109. https://doi.org/10.1016/j.jpcs.2022.111109
  25. Zhou B., Zhang C., Li Y. et al. // J. Colloid Interface Sci. 2025. V. 695. P. 137787. https://doi.org/10.1016/j.jcis.2025.137787
  26. Niu H., Zhao W., Lv H. et al. // Chem. Eng. J. 2021. V. 411. P. 128400. https://doi.org/10.1016/j.cej.2020.128400
  27. Jun Y.-S., Lee E.Z., Wang X. et al. // Adv. Funct. Mater. 2013. V. 23. N. 29. P. 3661. https://doi.org/10.1002/adfm.201203732
  28. Praus P., Smýkalová A., Foniok K. et al. // J. Environ. Chem. Eng. 2021. V. 9. N. 4. P. 105498. https://doi.org/10.1016/j.jece.2021.105498
  29. Kharina S., Kurenkova A., Aydakov E. et al. // Appl. Surf. Sci. 2025. V. 698. P. 163074. https://doi.org/10.1016/j.apsusc.2025.163074
  30. Lu W., Xu L., Shen X. et al. // Chem. Eng. J. 2023. V. 472. P. 144708. https://doi.org/10.1016/j.cej.2023.144708
  31. Wierzyńska E., Pisarek M., Lecki T. et al. // Molecules. 2023. V. 28. N. 6. P. 2469. https://doi.org/10.3390/molecules28062469
  32. Kopoleva E., Lebedev M.D., Postovalova A. et al. // Nano. Lett. 2023. V. 23. N. 23. P. 10811. https://doi.org/10.1021/acs.nanolett.3c02933
  33. Kong K., Zhong H., Chen D. et al. // Green Energy Env. 2025. V. 10. N. 7. P. 1551. https://doi.org/10.1016/j.gee.2025.01.004
  34. Vandeputte A.G., Reyniers M.-F., Marin G.B. // J. Phys. Chem. A. 2010. V. 114. N. 39. P. 10531. https://doi.org/10.1021/jp103357z
  35. Xu L., Li L., Hu Z. et al. // J. Catal. 2023. V. 418. P. 300. https://doi.org/10.1016/j.jcat.2023.01.019
  36. Алексеев К.Д., Сизых М.Р., Батоева А.А. // Изв. вузов. 2024. Т. 67. С. 123. https://doi.org/10.6060/ivkkt.20246712.7082

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