Ionic and phase compositions of nanosized y2.5ce0.5fe2.5ga2.5o12 film on gd3ga5o12 substrate

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Abstract

The ionic and phase compositions of the nanosized Y2.5Ce0.5Fe2.5Ga2.5O12 ferrogarnet film obtained by double ion-beam deposition/sputtering on a Gd3Ga5O12 substrate were studied using X-ray diffraction analysis and X-ray photoelectron spectroscopy. The target for film production was obtained by gel combustion followed by annealing in vacuum. The X-ray diffraction results confirmed the phase homogeneity of Y2.5Ce0.5Fe2.5Ga2.5O12 both in powder and in films form and the absence of cerium dioxide impurity. At the same time, according to X-ray photoelectron spectroscopy, along with Ce3+, Ce4+ ions are present on the surface of the Y2.5Ce0.5Fe2.5Ga2.5O12 film.

About the authors

Y. A. Teterin

Lomonosov Moscow State University; National Research Center “Kurchatov Institute,”

Email: ketsko@igic.ras.ru

K. I. Maslakov

Lomonosov Moscow State University

Email: ketsko@igic.ras.ru

A. I. Serokurova

Scientific and Practical Center on Materials Science, National Academy of Sciences of Belarus

Email: ketsko@igic.ras.ru

M. N. Smirnova

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: ketsko@igic.ras.ru

G. E. Nikiforova

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: ketsko@igic.ras.ru

N. N. Novitskiy

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: ketsko@igic.ras.ru

S. A. Sharko

Scientific and Practical Center on Materials Science, National Academy of Sciences of Belarus

Email: ketsko@igic.ras.ru

A. Y. Teterin

Lomonosov Moscow State University

Email: ketsko@igic.ras.ru

M. N. Markelova

Lomonosov Moscow State University

Email: ketsko@igic.ras.ru

V. A. Amelichev

OOO “S-Innovations”

Email: ketsko@igic.ras.ru

V. A. Ketsko

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Author for correspondence.
Email: ketsko@igic.ras.ru

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