Synthesis and physicochemical properties of magnetic Fe3O4 particles doped with Gd(III)

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Abstract

Magnetic Fe3O4 nanoparticles were synthesized by alkaline precipitation of aqueous solutions of divalent and trivalent iron salts. Synthesis of Fe3−xGdxO4 nanoparticles (x = 0.05; 0.1) was performed by adding a calculated amount of Gd(NO3)3 6H2O to the initial solution of iron salt mixture. The phase composition and magnetic properties of the synthesized powders were investigated by X-ray phase analysis, Mössbauer spectroscopy on 57Fe isotope and magnetometry at temperatures T = 7, 20 and 300 K. The investigations confirmed the formation of nanoparticles of non-stehiometric Fe3−δO4 magnetite, as well as magnetite doped with Gd3+ ions. The correlation between the average diameter of nanoparticles of the initial Fe3−δO4 powder and doped Fe3−xGdxO4 powder and the salt used in the synthesis, as well as the concentration of Gd (x), respectively, was revealed.

About the authors

Y. D. Mitskevich

Belarusian State University

Email: fcfvvv12@gmail.com
Minsk, 220030 Belarus

M. M. Degtyarik

Research Institute for Physical Chemical Problems of the Belarusian State University

Email: fcfvvv12@gmail.com
Minsk, 220030 Belarus

A. A. Kharchenko

Research Institute of Nuclear Problems of the Belarusian State University

Email: fcfvvv12@gmail.com
Minsk, 220030 Belarus

M. V. Bushinsky

Practical Center of the National Academy of Sciences of Belarus for Materials Science

Email: fcfvvv12@gmail.com
Minsk, 220072 Belarus

J. A. Fedotova

Research Institute of Nuclear Problems of the Belarusian State University

Author for correspondence.
Email: fcfvvv12@gmail.com
Minsk, 220030 Belarus

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