CRYSTAL STRUCTURE OF INTERMETALLIC COMPOUNDS IN SYSTEMS Pd–(Cu, Ag, Au)–(In, Sn)

Cover Page

Cite item

Full Text

Abstract

The crystal structure of ternary intermetallic compounds τ1 in the Pd-(Cu, Ag, Au)-Sn systems has been determined. It has been established that in the silver and gold systems they crystallize in a body-centered tetragonal cell with an ordering of atoms corresponding to the Al3Ti structural type, and in the copper system for the τ1 phase the VRh2Sn structure is formed, which is its additionally ordered derivative. The data available in the literature and obtained by the authors on the structures of binary and ternary compounds, which are ordered derivatives of a Cu-type structure, in Pd systems with group 11 elements and non-transition metals In and Sn are generalized and analyzed. It has been shown that they are formed at certain values of electron concentration (e/a): with the AuCu or Al3Zr structure types at e/a = 0.75, with the Al3Ti and VRh2Sn structure type at e/a from 0.8 to 1, and with the AuCu3 structure type at e/a = 1. The size factor affects the direction and extent of phase homogeneity regions.

About the authors

E. G Kabanova

Lomonosov Moscow State University

Department of Chemistry Moscow, Russia

G. P Zhmurko

Lomonosov Moscow State University

Department of Chemistry Moscow, Russia

A. S Pavlenko

Lomonosov Moscow State University

Department of Chemistry Moscow, Russia

E. A Ptashkina

Lomonosov Moscow State University

Email: evgeniyaptashkina@gmail.com
Department of Chemistry Moscow, Russia

M. A Kareva

Lomonosov Moscow State University

Department of Chemistry Moscow, Russia

V. N Kuznetsov

Lomonosov Moscow State University

Department of Chemistry Moscow, Russia

References

  1. Wencka M., Hahne M., Kocjan A. et al. // Intermetallics. 2014. V. 55. P. 56. https://doi.org/10.1016/j.intermet.2014.07.007
  2. Акимова О.В., Овчаров А.В., Горбунов С.В. // Неорган. материалы. 2023. V. 59. № 11. P. 1326. https://doi.org/10.31857/S0002337X23110015
  3. Бумагин Н.А. // Журн. общ. химии. 2022. V. 92. № 1. Р. 102. https://doi.org/10.31857/S0044460X22010115
  4. Kareva M.A., Kabanova E.G., Kuznetsov V.N. et al. // Moscow Univ. Bull., Ser. Khim. 2011. V. 66. № 6. Р. 381. https://doi.org/10.3103/S0027131411060046
  5. Kareva M.A., Kabanova E.G., Kalmykov K.B. et al. // J. Phase Equilib. Diffus. 2014. V. 35. № 4. Р. 413. https://doi.org/10.1007/s11669-014-0299-5
  6. Ptashkina E.A., Kabanova E.G., Yatsenko A.V. et al. // J. Alloys Compd. 2019. V. 776. P. 620. https://doi.org/10.1016/j.jallcom.2018.10.282
  7. Ptashkina E.A., Kabanova E.G., Kalmykov K.B. et al. // J. Alloys Compd. 2020. V. 845. P. 156166. https://doi.org/10.1016/j.jallcom.2020.156166
  8. Pavlenko A.S., Ptashkina E.A., Zhmurko G.P. et al. // Russ. J. Phys. Chem. A. 2023. V. 97. P. 42. https://doi.org/10.1134/S0036024423010235
  9. Zemanova A., Semenova O., Kroupa A. et al. // Monatsh. Chem. 2005. V. 136. № 11. P. 1931. https://doi.org/10.1007/s00706-005-0384-x
  10. Zemanova A., Semenova O., Kroupa A. et al. // Intermetallics. 2007. V. 15. P. 77. https://doi.org/10.1016/j.intermet.2006.03.002
  11. Pavlenko A.S., Ptashkina E.A., Kabanova E.G. et al. // Calphad. 2023. V. 81. P. 102533. http://doi.org/10.1016/j.calphad.2023.102533
  12. Bhan S., Schubert K. // J. Less Common. Met. 1969. V. 17. P. 73. http://doi.org/10.1016/0022-5088(69)90038-1
  13. Kohlmann H., Ritter C. // Z. Naturforsch., B: Chem. Sci. 2007. V. 62. P. 929. http://doi.org/10.1515/znb-2007-0709
  14. Kohlmann H., Ritter C. // Z. Anorg. Allg. Chem. 2009. V. 635. P. 1573. http://doi.org/10.1002/zaac.200900053
  15. Hellner E., Laves F. // Z. Naturforsch. A. 1947. V. 2. № 3. P. 177. https://doi.org/10.1515/zna-1947-0310
  16. Prince E. International Tables for Crystallography. V. C: Mathematical, physical and chemical tables. Dordrecht: Kluwer Academic Publ., 2004.
  17. Schubert K. // Int. J. Mater. Res. 1952. V. 43. № 1. P. 1. https://doi.org/10.1515/ijmr-1952-430101
  18. Schubert K. // Int. J. Mater. Res. 1955. V. 46. № 1. P. 43. https://doi.org/10.1515/ijmr-1955-460109
  19. Roy N., Kuila Harshit S.K., Pramanik P. et al. // Eur. J. Inorg. Chem. 2022. V. 26. P. 202200309. https://doi.org/10.1002/ejic.202200309
  20. Amundsen M., Pike N.A., L0vvik O.M. et al. // Materialia. 2022. V. 24. P. 101461. https://doi.org/10.1016/j.mtla.2022.101461
  21. STOE WinXPOW. Version 2.24 [электронный ресурс]. Software package (10.2 Mb). STOE & Cie GmbH: Darmstadt, 2009.
  22. Rodriguez-Carvajal J. // Abstracts of the Satellite Meeting on Powder Diffraction of the XV Congress of the IUCr, Toulouse, France. 1990. P. 127.
  23. Xu J.-H., Lin W., Freeman A.J. // Phys. Rev. B. 1993. V. 48. № 7. Р. 4276. https://doi.org/10.1103/PhysRevB.48.4276
  24. Guo Sh., Ng Ch., Lu J. et al. // J. Appl. Phys. 2011. V. 109. № 10. P. 103505. https://doi.org/10.1063/1.3587228
  25. Mizutani U. // MRS Bulletin. 2012. V. 37. № 2. P. 169. https://doi.org/10.1557/mrs.2012.45
  26. Kohlmann H., Skripov A.V., Soloninin A.V. et al. // J. Solid State Chem. 2010. V. 183. № 2. P. 2461. http://doi.org/10.1016/j.jssc.2010.08.015
  27. Пирсон У. Кристаллохимия и физика металлов и сплавов / Пер. с англ. канд. физ.-мат. наук С.Н. Горина. М.: Мир, 1977.
  28. Pyykko P. // Chem. Soc. Rev. 2008. V. 37. P. 1967. http://doi.org/10.1039/b708613j

Supplementary files

Supplementary Files
Action
1. JATS XML
Download

Copyright (c) 2024 Russian Academy of Sciences

Согласие на обработку персональных данных

 

Используя сайт https://journals.rcsi.science, я (далее – «Пользователь» или «Субъект персональных данных») даю согласие на обработку персональных данных на этом сайте (текст Согласия) и на обработку персональных данных с помощью сервиса «Яндекс.Метрика» (текст Согласия).