Influence of Ionic Liquid on the Extraction of Actinides and Lanthanides(III) with Phosphorylureas from Nitric Acid Solutions
- Authors: Turanov A.N.1, Karandashev V.K.2, Goryunov E.I.3, Goryunova I.B.3, Brel V.K.3
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Affiliations:
- Osipyan Institute of Solid State Physics of the Russian Academy of Sciences
- Institute of Microelectronics Technology and High Pure Materials of the Russian Academy of Sciences
- Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
- Issue: Vol 69, No 8 (2024)
- Pages: 1174-1180
- Section: ФИЗИКОХИМИЯ РАСТВОРОВ
- URL: https://journals.rcsi.science/0044-457X/article/view/274338
- DOI: https://doi.org/10.31857/S0044457X24080107
- EDN: https://elibrary.ru/XJLMSF
- ID: 274338
Cite item
Abstract
The effect of the ionic liquid 1-butyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl]imide on the extraction of U(VI), Th(IV) and lanthanides(III) from nitric acid solutions with phosphorylureas RR'P(O)NHC(O)NHC8H17 n differing in the nature of the substituents at the phosphorus atom was studied. A significant synergistic effect was discovered during the extraction of metal ions in the presence of an ionic liquid in the organic phase. The stoichiometry of the extracted complexes was determined. The influence of the structure of the extractant, the nature of the organic diluent, and the concentration of HNO3 in the aqueous phase on the efficiency of the extraction of metal ions into the organic phase is considered.
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About the authors
A. N. Turanov
Osipyan Institute of Solid State Physics of the Russian Academy of Sciences
Author for correspondence.
Email: v_brel@mail.ru
Russian Federation, Chernogolovka
V. K. Karandashev
Institute of Microelectronics Technology and High Pure Materials of the Russian Academy of Sciences
Email: v_brel@mail.ru
Russian Federation, Chernogolovka
E. I. Goryunov
Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Email: v_brel@mail.ru
Russian Federation, Moscow
I. B. Goryunova
Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Email: v_brel@mail.ru
Russian Federation, Moscow
V. K. Brel
Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Email: v_brel@mail.ru
Russian Federation, Moscow
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