Synthesis, Crystal Structure and Magnetic Properties of Y3–xCex(Fe0.5Ga0.5)5O12 (х = 0, 0.5)
- Authors: Romanova Е.S.1, Smirnova M.N.1, Nikiforova G.E.1, Ketsko V.A.1, Yanushkevich K.I.2
-
Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
- Scientific and Practical Center for Materials Science of the National Academy of Sciences of Belarus
- Issue: Vol 69, No 8 (2024)
- Pages: 1104-1108
- Section: СИНТЕЗ И СВОЙСТВА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
- URL: https://journals.rcsi.science/0044-457X/article/view/274243
- DOI: https://doi.org/10.31857/S0044457X24080022
- EDN: https://elibrary.ru/XKYNPW
- ID: 274243
Cite item
Abstract
The specific magnetisation and magnetic susceptibility of ferrogranates of the composition Y3–xCex(Fe0.5Ga0.5)5O12 (x = 0, 0.5) obtained by the gel combustion method have been measured. It was found that after synthesis and subsequent crystallisation at pressure ≈ 10–2 Pa at 1023 K for 2 h, the temperature of magnetic phase transformation in the studied compositions Y3–xCex(Fe0.5Ga0.5)5O12 increases with the replacement of yttrium ions Y3+ by Ce3+. Partial substitution of iron ions in the ferrogranate lattice by gallium leads to the appearance of antiferromagnetic ordering with sufficiently high Curie-Weiss temperature Θef.
Keywords
Full Text

About the authors
Е. S. Romanova
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Email: ketsko@igic.ras.ru
Russian Federation, Moscow
M. N. Smirnova
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Email: ketsko@igic.ras.ru
Russian Federation, Moscow
G. E. Nikiforova
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Email: ketsko@igic.ras.ru
Russian Federation, Moscow
V. A. Ketsko
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Author for correspondence.
Email: ketsko@igic.ras.ru
Russian Federation, Moscow
K. I. Yanushkevich
Scientific and Practical Center for Materials Science of the National Academy of Sciences of Belarus
Email: ketsko@igic.ras.ru
Belarus, Minsk
References
- Никитов С.А., Сафин А.Р., Калябин Д.В. и др. // УФН. 2020. Т. 190. № 10. С. 1009. https://doi.org/10.3367/UFNr.2019.07.038609
- Barman A., Gubbiotti G., Ladak S. et al. // J. Phys.: Condens. Matter. 2021. V. 33. P. 413001. https://doi.org/10.1088/1361-648X/abec1a
- Xiong D., Jiang Y., Shi K. et al. // Fundamental Research. 2022. V. 2. P. 522. https://doi.org/10.1016/j.fmre.2022.03.016
- Chumak A.V., Kabos P., Fellow L. et al. // IEEE Trans. Magn. 2022. V. 58. № 6. P. 0800172. https://doi.org/10.1109/TMAG.2022.3149664.
- Garskaite E., Gibson K., Leleckaite A. et al. // Chem. Phys. 2006. V. 323. P. 204. https://doi.org/10.1016/j.chemphys.2005.08.055
- McCloy J.S., Walsh B. // IEEE Trans. Magn. 2013. V. 49. № 7. P. 4253. https://doi.org/10.1109/TMAG.2013.2238510.
- Park M.B., Cho N.H. // J. Magn. Magn. Mater. 2001. V. 231. P. 253. https://doi.org/10.1016/S0304-8853(01)00068-3
- Shen T., Dai H., Song M. // J. Supercond. Nov. Magn. 2017. V. 30. P. 937. https://doi.org/10.1007/s10948-016-3880-9
- Gomi M., Furuyama H., Abe M. // J. Appl. Phys. 1991. V. 70. P. 7065. https://doi.org/10.1063/1.349786
- Рандошкин В.В., Червоненкис А.Я. // Прикладная магнитооптика. М.: Энергоатомиздат, 1990. 320 с.
- Shen T., Dai H., Song M. // J. Supercond. Nov. Magn. 2017. V. 30. P. 937. https://doi.org/10.1007/s10948–016–3880–9
- Huang M., Zhang S. // Appl. Phys. A. 2022. V. 74. P. 177. https://doi.org/10.1007/s003390100883
- Onbasli M. C., Beran L., Zahradnik M. et al. // Scientific Reports. 2016. Т. 6. № 1. С. 23640. https://doi.org/10.1038/srep23640
- Shen T., Dai H., Song M. // J. Supercond. Nov. Magn. 2017. V. 30. P. 937. https://doi.org/10.1007/s10948-016-3880-9
- Sharm V., Kuanr B.K. // J. Alloys Compd. 2018. V. 748. P. 591. https://doi.org/10.1016/j.jallcom.2018.03.086
- Huang M., Zhang S. // Appl. Phys. A. 2002. V. 74. P. 177. https://doi.org/10.1007/s003390100883
- Smirnova M.N., Glazkova I.S., Nikiforova G.E. et al. // Nanosystems: Physics, Chemistry, Mathematics. 2021. V. 12. № 2. P. 210. https://doi.org/10.17586/2220-8054-2021-12-2-210-217
- Teterin Yu.A., Smirnova M.N., Maslakov K.I. et al. // Dokl. Phys. Chem. 2022. V. 503. P. 45. https://doi.org/10.1134/S0012501622040029
- Тетерин Ю.А., Смирнова М.Н., Маслаков К.И. и др. // Журн. неорган. химии. 2023. Т. 68. № 7. С. 904. https://doi.org/10.31857/S0044457X23600135
- Смирнова М.Н., Копьева М.А., Береснев Э.Н. и др. // Журн. неорган. химии. 2018. Т. 63. С. 411. https://doi.org/10.1134/S0036023618040198
- Смирнова М.Н., Кондратьева О.Н., Никифорова Г.Е., Хорошилов А.В. // Журн. неорган. химии. 2023. Т. 68. № 5. С. 581. https://doi.org/10.31857/S0044457X22602383
- Маковецкий Г.И., Галяс А.И., Богуш А.К. и др. // Вести НАН Беларуси. Сер. физ.-тех. наук. 2000. № 3. С. 10.
- Winkler G. Magnetic Garnets. F. Viroeand Sohn: Braunshweig/Wiesbaden. 1981. 735 p.
- Крупичка С. Физика ферритов и родственных им магнитных окислов. М.: Мир, 1976. Т. 1. 360 с.
- Gu B.X., Zhang H.Y., Wang H., Zhai H.R. // J. Magn. Magn. Mater. 1997. V. 168. P. 31. https://doi.org/10.1016/S0304-8853(96)00696-8
- Scott G.B., Lacklison D.E., Page J.L. // J. Phys. C: Solid State Phys. 1975. V. 8. P. 519. https://doi.org/10.1103/PhysRevB.10.971
Supplementary files
