Polycation perovskites in the system Ba2Y2O5–BaCuO2–BaMoO4–BaTiO3
- Authors: Smirnova M.N.1, Kopeva M.A.1, Nipan G.D.1, Nikiforova G.E.1, Yapryntsev A.D.1, Arkhipenko A.A.1
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Affiliations:
- Kurnakov Institute of general and inorganic chemistry of the Russian Academy of Sciences
- Issue: Vol 69, No 7 (2024)
- Pages: 981-985
- Section: СИНТЕЗ И СВОЙСТВА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
- URL: https://journals.rcsi.science/0044-457X/article/view/274221
- DOI: https://doi.org/10.31857/S0044457X24070054
- EDN: https://elibrary.ru/XOMJFI
- ID: 274221
Cite item
Abstract
To maintain the single-phase nature of the cubic solid solution Ba2(Y,Cu,Mo)2O6, which is prone to polymorphism, titanium oxide was used. As a result of the synthesis by burning the gel, annealing at 1000°C and subsequent cooling in an inertial thermal mode, the cubic modification F3m without an admixture of perovskite Fm3m for the composition Ba5Y2CuMoTiO14 was obtained for the first time. A comparative study of samples Ba4Y2CuMoO11 and Ba5Y2CuMoTiO14 was carried out using the methods of X-ray phase analysis, X-ray fluorescence spectrometry, infrared spectroscopy and diffuse reflectance spectroscopy.
Keywords
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About the authors
M. N. Smirnova
Kurnakov Institute of general and inorganic chemistry of the Russian Academy of Sciences
Author for correspondence.
Email: smirnova_macha1989@mail.ru
Russian Federation, Moscow, 119991
M. A. Kopeva
Kurnakov Institute of general and inorganic chemistry of the Russian Academy of Sciences
Email: smirnova_macha1989@mail.ru
Russian Federation, Moscow, 119991
G. D. Nipan
Kurnakov Institute of general and inorganic chemistry of the Russian Academy of Sciences
Email: smirnova_macha1989@mail.ru
Russian Federation, Moscow, 119991
G. E. Nikiforova
Kurnakov Institute of general and inorganic chemistry of the Russian Academy of Sciences
Email: smirnova_macha1989@mail.ru
Russian Federation, Moscow, 119991
A. D. Yapryntsev
Kurnakov Institute of general and inorganic chemistry of the Russian Academy of Sciences
Email: smirnova_macha1989@mail.ru
Russian Federation, Moscow, 119991
A. A. Arkhipenko
Kurnakov Institute of general and inorganic chemistry of the Russian Academy of Sciences
Email: smirnova_macha1989@mail.ru
Russian Federation, Moscow, 119991
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