Synthesis of Boron Nitride by Reduction of Boron Oxide with Aluminum in Nitrogen

D. A. Tkachev; Ткачев Д. А.; M. Kh. Ziatdinov; Зиатдинов М. Х.; I. A. Zhukov; Жуков И. А.; V. A. Litvinova; Литвинова В. А.; I. A. Belchikov; Бельчиков И. А.; N. G. Kravtsov; Кравцов Н. Г.

doi:10.31857/S0044457X23600354

Synthesis of Boron Nitride by Reduction of Boron Oxide with Aluminum in Nitrogen

Authors: Tkachev D.A.¹, Ziatdinov M.K.¹, Zhukov I.A.¹, Litvinova V.A.², Belchikov I.A.¹, Kravtsov N.G.¹
Affiliations:
1. Tomsk State University
2. Tomsk State University of Architecture and Building
Issue: Vol 68, No 10 (2023)
Pages: 1405-1412
Section: СИНТЕЗ И СВОЙСТВА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
URL: https://journals.rcsi.science/0044-457X/article/view/140306
DOI: https://doi.org/10.31857/S0044457X23600354
EDN: https://elibrary.ru/AJOUQB
ID: 140306

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Abstract
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Abstract

The paper presents the results of studies of the self-propagating high temperature synthesis (SHS) of boron nitride via chemical reduction of boron oxide with aluminum in a nitrogen medium. The phase composition of the powder reaction products depending on the nitrogen pressure during the synthesis was studied by X-ray diffraction. It was found that SHS in the B2O3–Al system gives the BN–Al2O3 powder material containing 20–28 wt % hexagonal boron nitride depending on the nitrogen pressure. Microstructure examination showed that the obtained powder materials contains separate hexagonal BN particles with <3 μm size. The differences in the density and morphology of BN and Al2O3 determine the possibility of BN isolation from the obtained powder mixture by the pneumatic powder separation methods.

Keywords

self-propagating high-temperature synthesis, powder materials, hexagonal boron nitride, phase composition

References

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