Sodium Chromium Arsenate Phosphates: Preparation, Structure, and Thermal Properties

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Abstract

Arsenate phosphates 
 (1.75 ≤ x ≤ 3.0) were prepared by coprecipitation. Their unit cell parameter was a linear function of composition: a (Å) = 0.0967x + 11.873. The Na3Cr2(AsO4)2PO4 crystal structure was refined by the Rietveld method; the coordinates of basal atoms and bond lengths were calculated. A garnet solid solution crystallizes at 600–650°C; transition to a high−temperature rhombohedral structure occurred at 994–1044°C. The thermal expansion of the low-temperature phase having a garnet structure was studied in the range from –130 to 200°C. The solid solution samples expanded isotropically and had small thermal expansion.

About the authors

E. A. Pyaterikov

Nizhny Novgorod State University

Email: piaterikovegor@gmail.com
603950, Nizhny Novgorod, Russia

V. I. Pet’kov

Nizhny Novgorod State University

Email: piaterikovegor@gmail.com
603950, Nizhny Novgorod, Russia

D. G. Fukina

Nizhny Novgorod State University

Email: piaterikovegor@gmail.com
603950, Nizhny Novgorod, Russia

E. Yu. Borovikova

Kola Scientific Center, Russian Academy of Sciences

Author for correspondence.
Email: piaterikovegor@gmail.com
184209, Apatity, Russia

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Copyright (c) 2023 Е.А. Пятериков, В.И. Петьков, Д.Г. Фукина, Е.Ю. Боровикова

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