Optical Properties of Fluorozirconate Glasses Doped with Chromium Ions

S. Kh. Batygov; Батыгов С. Х.; M. N. Brekhovskikh; Бреховских М. Н.; L. V. Moiseeva; Моисеева Л. В.; V. V. Vinokurova; Винокурова В. В.; N. Yu. Kirikova; Кирикова Н. Ю.; V. A. Kondratyuk; Кондратюк В. А.; V. N. Makhov; Махов В. Н.

doi:10.31857/S0044457X23600603

Optical Properties of Fluorozirconate Glasses Doped with Chromium Ions

Authors: Batygov S.K.¹, Brekhovskikh M.N.², Moiseeva L.V.¹, Vinokurova V.V.², Kirikova N.Y.³, Kondratyuk V.A.³, Makhov V.N.³
Affiliations:
1. Prokhorov General Physics Institute, Russian Academy of Sciences
2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
3. Lebedev Physical Institute, Russian Academy of Sciences
Issue: Vol 68, No 8 (2023)
Pages: 1119-1125
Section: НЕОРГАНИЧЕСКИЕ МАТЕРИАЛЫ И НАНОМАТЕРИАЛЫ
URL: https://journals.rcsi.science/0044-457X/article/view/136418
DOI: https://doi.org/10.31857/S0044457X23600603
EDN: https://elibrary.ru/MYQKRN
ID: 136418

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Abstract

Chromium trifluoride-doped fluoride glasses in the ZrF4–BaF2–LaF3–AlF3–NaF (ZBLAN) system with partial substitution of fluorine for chlorine have been synthesized. The spectral data obtained confirm that chromium ions enter the glass structure and exhibit broadband luminescence caused by the 4T2 → 4A2 transition in the Cr3+ ion. The observed long-wavelength shift of the broadband luminescence band and Cr3+absorption bands in fluoride–chloride glass compared to fluoride glass corresponds to the expected behavior of the Cr3+ luminescence and absorption spectra when fluoride ions are replaced by chloride ions, which should lead to a weakening of the strength of the crystal field acting on Cr3+ ions. At room temperature, the luminescence of Cr3+ ions at 888 and 908 nm is strongly quenched due to the thermally stimulated nonradiative transition from the 4T2 excited state to the 4A2 ground state.

Keywords

fluorozirconate glasses, chromium ions, luminescence, optical absorption, temperature quenching

References

Drexhage M.G., Moynihan C.T. // Sci. Am. 1988. V. 259. P. 110.
Boulard B. // Functionalized Inorganic Fluorides. Ch. 11. Jonn Wiley & Sons. Ltd. UK, 2010. P. 538.
Lucas J., Smektala F., Adam J.-L. // J. Fluorine Chem. 2002. V. 114. P. 113. https://doi.org/10.1016/S0022-1139(02)00016-7
Poulain M., Cozic S., Adam J.-L. in Mid-Infrared Fiber Photonics Glass Materials, Fiber Fabrication and Processing, Laser and Nonlinear Sources, Woodhead Publishing Series in Electronic and Optical Materials, 2022. P. 47.
Батыгов С.Х., Бреховских М.Н., Моисеева Л.В. и др. // Неорган. материалы. 2019. Т. 55. № 11. С. 1254. https://doi.org/10.1134/S0002337X19110022
Brekhovskikh M.N., Batygov S.Kh., Moiseeva L.V. et al. // Phys. Status Solidi B. 2020. V. 257. P. 1900457. https://doi.org/10.1002/pssb.201900457
Батыгов С.Х., Бреховских М.Н., Моисеева Л.В. и др. // Журн. неорган. химии. 2021. Т. 66. № 10. С. 1491. https://doi.org/10.31857/S0044457X21100020
Бреховских М.Н., Кирикова Н.Ю., Моисеева Л.В. и др. // Журн. неорган. химии. 2022. Т. 67. № 7. С. 1022. https://doi.org/10.31857/S0044457X22070042
Lachheb R., Herrmann A., Damak K. et al. // J. Lumin. 2017. V. 186. P. 152. https://doi.org/10.1016/j.jlumin.2017.02.030
Fu W., Zhang C., Li Z. et al. Ceram. Int. 2020. V. 46. P. 15054. https://doi.org/10.1016/j.ceramint.2020.03.038
Marciniak L., Bednarkiewicz A., Kowalska D. et al. // J. Mater. Chem. C. 2016. P. 5559. https://doi.org/10.1039/C6TC01484D
Marciniak L., Bednarkiewicz A., Strek W. // Sens. Actuators, B: Chem. 2017. V. 238. P. 381. https://doi.org/10.1016/j.snb.2016.07.080
Marciniak L., Bednarkiewicz A. // Sens. Actuators, B: Chem. 2017. V. 243. P. 388. https://doi.org/10.1016/j.snb.2016.07.080
Chen D., Liu S., Xu W. et al. // J. Mater. Chem. C. 2017. V. 5 P. 11769. https://doi.org/10.1039/C7TC04410K
Kowalska K., Kuwik M., Polak J. et al. // J. Lumin. 2022. V. 245. P. 118775. https://doi.org/10.1016/j.jlumin.2022.118775
Ramadevudu G., Chary M.N., Shareefuddin M. // Mater. Chem. Phys. 2017. V. 186. P. 382. https://doi.org/10.1016/j.matchemphys.2016.11.009
Maalej O., Taktak O., Boulard B. et al. // J. Phys. Chem. B. 2016. V. 120. P. 7538. https://doi.org/10.1021/acs.jpcb.6b03230
Taktak O., Souissi H., Souha K. // J. Lumin. 2015. V. 161. P. 368. https://doi.org/10.1016/j.jlumin.2015.01.047
Хайдуков Н.М., Никонов К.С., Бреховских М.Н. и др. // Неорган. материалы. 2022. Т. 58. № 7. С. 778. https://doi.org/10.31857/S0002337X22070107
Tanabe Y., Sugano S. // J. Phys. Soc. Jpn. 1954. V. 9. P. 776. https://doi.org/10.1143/JPSJ.9.766
Adachi S. ECS J. Solid State Sci. Technol. 2019. V. 8. R 164.https://doi.org/10.1149/2.0061912jss
Bunuel M.A., Alcalá R., Cases R. // Solid State Commun. 1998. V. 107. P. 491. https://doi.org/10.1016/S0038-1098(98)00248-8
Fano U. // Phys. Rev. 1961. V. 124. P. 1866. https://doi.org/10.1103/PhysRev.124.1866
Batygov S., Brekhovskikh M., Moiseeva L. et al. // J. Non-Cryst. Solids. 2018. V. 480. P. 57. https://doi.org/10.1016/j.jnoncrysol.2017.06.029
Henderson B., Imbush G.F. // Opt. Spectrosc. Inorg. Solids. Oxford: Clarendon Press, 2006. 645 p.
Adachi S. // ECS J. Solid State Sci. Technol. 2021. V. 10. P. 026001. https://doi.org/10.1149/2162-8777/abdc01
Adachi S. // ECS J. Solid State Sci. Technol. 2021. V. 10. P. 036001. https://doi.org/10.1149/2162-8777/abdfb7