Optimization of Liquid Complex Fertilizer Formulations Using Phase Diagrams of Multicomponent Systems
- Authors: Kudryashova O.S.1,2, Kistanova N.S.3,1, Elokhov A.M.3,1
-
Affiliations:
- Natural Sciences Institute at Perm State Research University
- Perm State Agro-Technological University
- Perm State Research University
- Issue: Vol 68, No 8 (2023)
- Pages: 1083-1089
- Section: ФИЗИКО-ХИМИЧЕСКИЙ АНАЛИЗ НЕОРГАНИЧЕСКИХ СИСТЕМ
- URL: https://journals.rcsi.science/0044-457X/article/view/136411
- DOI: https://doi.org/10.31857/S0044457X23600445
- EDN: https://elibrary.ru/MZDWAA
- ID: 136411
Cite item
Abstract
The paper describes a method for the optimization of liquid complex fertilizer (LCF) formulations using phase diagrams of multicomponent water–salt systems. The chosen optimization criteria are the concentration of solution and the set of salts that provide the most concentrated fertilizer at the set ratio N : P2O5 : K2O. The opportunities of the method are shown for exemplary three- and four-component systems. The compositions of eutonic solutions and the ratios of nutrients calculated for them are given. Experimental data confirm the influence of the salt set and a solubilizer (urea) on the solution concentration. The number of optimal compositions becomes greater as the number of components in the system increases. Phase diagrams help to determine whether the liquid fertilizer composition belongs to the 15 homogeneous regions and thereby to guarantee its long-term storage stability.
About the authors
O. S. Kudryashova
Natural Sciences Institute at Perm State Research University; Perm State Agro-Technological University
Email: oskudr55@gmail.com
614990, Perm, Russia; 614990, Perm, Russia
N. S. Kistanova
Perm State Research University; Natural Sciences Institute at Perm State Research University
Email: oskudr55@gmail.com
614990, Perm, Russia; 614990, Perm, Russia
A. M. Elokhov
Perm State Research University; Natural Sciences Institute at Perm State Research University
Author for correspondence.
Email: oskudr55@gmail.com
614990, Perm, Russia; 614990, Perm, Russia
References
- Ягодин Б.А., Жуков Ю.П., Кобзаренко В.И. Агрохимия. СПб.: Лань, 2023. 584 с.
- Roy R.N., Finck A., Blair G.J., Tandon H.L.S. // Fertilizer and plant nutrition bulletin, N 16. Food and agriculture organization of the United Nations. Rome, 2006. 366 p.
- Позин М.Е. Технология минеральных удобрений. Л.: Химия, 1983. С. 329.
- Кистанова Н.С., Кудряшова О.С., Мазунин С.А. и др. Способ определения составов высококонцентрированных жидких комплексных удобрений. Пат. 2529163 (RU), 2014. Б.И. № 27.
- Navizaga C., Boecker J., Sviklas A.M. et al. // ACS Sustainable Chem. Eng. 2017. № 5. P 1747. https://doi.org/10.1021/acssuschemeng.6b02511
- Baltrusaitis J., Sviklas A.M., Galeckiene J. // ACS Sustainable Chem. Eng. 2014. V. 2. № 10. P. 2477. https://doi.org/https://doi.org/10.1021/sc500512b
- Baltrusaitis J., Sviklas A.M. // ACS Sustainable Chem. Eng. 2015. V. 3. № 7. P. 1544. https://doi.org/10.1021/acssuschemeng.5b00241
- Dittmar H., Drach M., Vosskamp R. at. al. Ullmann’s Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. 2009. https://doi.org/10.1002/14356007.n10_n01
- Мазунин С.А., Носков М.Н., Елсуков А.В. // Журн. неорган. химии. 2017. Т. 62. № 5. С. 539. https://doi.org/10.7868/S0044457X17050178
- Справочник по растворимости // Отв. редактор Кафаров В.В. Л.: Наука, 1970. Т. 3. Кн. 1–3.
- Кудряшова О.С., Катаев А.В., Малинина Л.Н. // Журн. неорган. химии. 2015. Т. 60. № 3. С. 405. https://doi.org/10.7868/S0044457X15030125
- Матвеева К.Р., Кудряшова О.С. // Журн. неорган. химии. 2009. Т. 54. № 7. С. 1200.
- Шабанов Р.А., Хазеев А.В., Кистанова Н.С. // Вестн. Пермск. ун-та. Сер. Химия. 2016. Вып. 3(23). С. 77. https://doi.org/10.17072/2223-1838-2016-3-77-84
- Носков М.Н., Мазунин С.А. // Журн. физ. химии. 2015 Т. 89. № 6. С. 971. https://doi.org/10.7868/S0044453715060217
- Кистанова Н.С., Коротких С.А. // Известия Саратовского университета. Новая серия. Сер. Химия. Биология. Экология. 2017. Т. 17. № 4. С. 389. https://doi.org/10.18500/1816-9775-2017-17-4-389-393
- Kamburova K.D., Kirilov P.P. // J. Chem. Eng. Data 2010. № 55. № 6. P. 2225. https://doi.org/https://doi.org/10.1021/je9007712
- Вольфкович С.И., Берлин Л.Е., Манцев Б.М. // Журн. прикл. химии. 1932. Т. 5. № 1. С. 1.
- Kistanova N.S., Mazunin S.A. // Russ. J. Inorg. Chem. 2020. V. 65. № 9. P. 1390. https://doi.org/https://doi.org/10.1134/S0036023620090077
- Чеснокова С.А., Кистанова Н.С. // Вестн. Пермск. ун-та. Сер. Химия. 2012. Т. 6. № 2. С. 55.
- Кистанова Н.С., Мазунин С.А., Фролова С.И., Блинов А.С. // Вестн. Тамбовск. техн. ун-та. 2010. Т. 16. № 4. С. 863.
- Носков М.Н., Мазунин С.А. // Вестн. Пермск. ун-та. Сер. Химия. 2015. Т. 18. № 2. С. 4.
- Deng W., Li T., Huang L. et al. // J. Solution Chem. 2023. V. 52. P. 201. https://doi.org/https://doi.org/10.1007/s10953-022-01224-5
- https://srdata.nist.gov/solubility/sol_detail.aspx?sysID=66_75
- Tang J., Mu R., Zhang B., Fan X. // J. Chem. Eng. Data. 2007. V. 52. № 4. P. 1179. https://doi.org/10.1021/je060346a
- Yang Z., Li J., Luo J. et al. // Fluid Phase Equilibria. 2012. V. 335. P. 60. https://doi.org/10.1016/j.fluid.2012.06.002
