Electrochemical Behavior of a Gold Electrode in the Aqueous Potassium Salt of Bridging 1,2,4,5-Tetraoxane

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Resumo

The behavior of a smooth gold electrode in aqueous solutions of the potassium salt of bridging 1,2,4,5-tetraoxane containing a biperoxide cyclic fragment was studied by cyclic voltammetry. The cathode process was analyzed in detail. It was shown that the process involves four electrons. The products of electrolysis of the potassium salt were studied, and a reaction mechanism was proposed.

Sobre autores

M. Polyakov

Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences

Email: SatPolyak@yandex.ru
119991, Moscow, Russia

M. Vedenyapina

Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences

Email: kuznvv@yandex.ru
119991, Moscow, Russia

A. Skundin

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: kuznvv@yandex.ru
119991, Moscow, Russia

I. Yaremenko

Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences

Email: kuznvv@yandex.ru
119991, Moscow, Russia

P. Radulov

Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences

Email: kuznvv@yandex.ru
119991, Moscow, Russia

V. Kuznetsov

Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences

Autor responsável pela correspondência
Email: kuznvv@yandex.ru
119991, Moscow, Russia

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Declaração de direitos autorais © М.В. Поляков, М.Д. Веденяпина, А.М. Скундин, И.А. Яременко, П.С. Радулов, В.В. Кузнецов, 2023

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