Kinetics and Dynamics of Sorption of the Glucose Target Molecule by a Molecularly Imprinted Polymer
- Authors: Garkushina I.S.1, Panyuta A.S.1
-
Affiliations:
- Institute of Macromolecular Compounds of the Russian Academy of Sciences
- Issue: Vol 97, No 12 (2023)
- Pages: 1699-1706
- Section: ХИМИЧЕСКАЯ КИНЕТИКА И КАТАЛИЗ
- URL: https://journals.rcsi.science/0044-4537/article/view/233055
- DOI: https://doi.org/10.31857/S0044453723120117
- EDN: https://elibrary.ru/YQKQZR
- ID: 233055
Cite item
Abstract
The effect of imprinting of a polymer matrix based on ethylene glycol dimethacrylate on the kinetics and dynamics of binding of the glucose target molecule has been studied. The contribution of the adsorption act to the sorption kinetics of the target sorbate by the molecularly imprinted polymer was established. Mixed-diffusion limitation of mass transfer and cooperative adsorption of glucose molecules during sorption by both imprinted and nonimprinted polymer granules were revealed. The binding rate and accessibility of sorption sites in the imprinted polymer were shown to increase, and frontal sorption occurred in a regular mode.
About the authors
I. S. Garkushina
Institute of Macromolecular Compounds of the Russian Academy of Sciences
Email: irin-g16@yandex.ru
199004, St. Petersburg, Russia
A. S. Panyuta
Institute of Macromolecular Compounds of the Russian Academy of Sciences
Author for correspondence.
Email: irin-g16@yandex.ru
199004, St. Petersburg, Russia
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