Selecting Reference States in Thermodynamic Descriptions of Non-Exchangeable Sorption

O. N. Khokhlova; Хохлова О. Н.; V. Yu. Khokhlov; Хохлов В. Ю.; S. A. Lisitsyna; Лисицына С. А.

doi:10.31857/S0044453723080101

Selecting Reference States in Thermodynamic Descriptions of Non-Exchangeable Sorption

Authors: Khokhlova O.N.¹, Khokhlov V.Y.¹, Lisitsyna S.A.¹
Affiliations:
1. Voronezh State University
Issue: Vol 97, No 8 (2023)
Pages: 1079-1083
Section: ХИМИЧЕСКАЯ ТЕРМОДИНАМИКА И ТЕРМОХИМИЯ
URL: https://journals.rcsi.science/0044-4537/article/view/136645
DOI: https://doi.org/10.31857/S0044453723080101
EDN: https://elibrary.ru/QUZFBX
ID: 136645

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Abstract
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Abstract

Selecting standard and reference states for a thermodynamic description of the non-exchange sorption of substances by ion exchangers is considered a stoichiometric process. It is shown that it is best to choose different reference states for free and sorption centers associated with the absorbed substance, since this allows calculations of the thermodynamic constants and energy characteristics of sorption. Results from calculating thermodynamic characteristics of sorption are presented and discussed for systems with the participation of amino acids (glycine and phenylalanine).

Keywords

thermodynamic descriptions, standard state, reference state, thermodynamic characteristics, non-exchange sorption, ion exchanger

References

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