Mechanism of the Thermolysis of Magnesium Perylenetetracarboxylates
- Authors: Naifert S.A.1, Zherebtsov D.A.1, Uchaev D.A.1, Morozov R.S.1, Smolyakova K.R.1, Orlova E.M.1, Pan’kova A.A.1, Sharova A.L.1
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Affiliations:
- South Ural State University
- Issue: Vol 97, No 6 (2023)
- Pages: 850-859
- Section: ФИЗИЧЕСКАЯ ХИМИЯ НАНОКЛАСТЕРОВ, СУПРАМОЛЕКУЛЯРНЫХ СТРУКТУР И НАНОМАТЕРИАЛОВ
- URL: https://journals.rcsi.science/0044-4537/article/view/136627
- DOI: https://doi.org/10.31857/S0044453723060201
- EDN: https://elibrary.ru/KCONVW
- ID: 136627
Cite item
Abstract
Black-red and orange magnesium perylene-3,4,9,10-tetracarboxylate species are synthesized in the ion-exchange reaction at room temperature and by boiling an aqueous solution, respectively. Upon heating the two species to 500°C in argon, they reversibly lose 19–27 wt % of their crystallization water, and the products become black. X-ray diffraction analysis results show the preservation of the layered structure upon heating, which is confirmed via transmission electron microscopy. Exposure to a humid atmosphere rehydrates and restores the original structure. Thermolysis to 1000°С in argon produces a composite of MgO nanoparticles in a porous glassy carbon matrix. The stability of perylenetetracarboxylates up to 500°C makes them a promising candidate for synthesizing metal–organic frameworks.
About the authors
S. A. Naifert
South Ural State University
Email: zherebtsov_da@yahoo.com
454080, Chelyabinsk, Russia
D. A. Zherebtsov
South Ural State University
Email: zherebtsov_da@yahoo.com
454080, Chelyabinsk, Russia
D. A. Uchaev
South Ural State University
Email: zherebtsov_da@yahoo.com
454080, Chelyabinsk, Russia
R. S. Morozov
South Ural State University
Email: zherebtsov_da@yahoo.com
454080, Chelyabinsk, Russia
K. R. Smolyakova
South Ural State University
Email: zherebtsov_da@yahoo.com
454080, Chelyabinsk, Russia
E. M. Orlova
South Ural State University
Email: zherebtsov_da@yahoo.com
454080, Chelyabinsk, Russia
A. A. Pan’kova
South Ural State University
Email: zherebtsov_da@yahoo.com
454080, Chelyabinsk, Russia
A. L. Sharova
South Ural State University
Author for correspondence.
Email: zherebtsov_da@yahoo.com
454080, Chelyabinsk, Russia
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