Membranes Based on PVdF–HFP and Alkylammonium Protic Ionic Liquids: Thermal and Transport Properties
- Authors: Shmukler L.E.1, Fadeeva Y.A.1, Stel’makh N.M.2, Safonova L.P.1
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Affiliations:
- Krestov Institute of Chemistry of Solutions, Russian Academy of Sciences
- Ivanovo State University of Chemical Technology
- Issue: Vol 97, No 1 (2023)
- Pages: 166-174
- Section: ФИЗИЧЕСКАЯ ХИМИЯ ПРОЦЕССОВ РАЗДЕЛЕНИЯ. ХРОМАТОГРАФИЯ
- URL: https://journals.rcsi.science/0044-4537/article/view/136543
- DOI: https://doi.org/10.31857/S0044453723010284
- EDN: https://elibrary.ru/BDDRGU
- ID: 136543
Cite item
Abstract
Casting from a solution is used to obtain proton-conducting membranes based on a poly(vinylidenefluoride-co-hexafluoropropylene) copolymer doped with diethylammonium hydrogen sulfate and diethylammonium mesylate with different levels of doping. An IR spectroscopic study is performed, and the phase behavior of the obtained membranes, their thermal and electrochemical stability, and specific electrical conductivity are investigated. It is established that doping protic ionic liquids into PVdF-HFP copolymer reduces the degree of its crystallinity. It has been shown that all membranes are thermally stable up to 290–300°C, and their conductivity at 145°C varies from 1.6 to 10.4 mS cm–1, depending on the level of doping.
About the authors
L. E. Shmukler
Krestov Institute of Chemistry of Solutions, Russian Academy of Sciences
Email: les@isc-ras.ru
153000, Ivanovo, Russia
Yu. A. Fadeeva
Krestov Institute of Chemistry of Solutions, Russian Academy of Sciences
Email: les@isc-ras.ru
153045, Ivanovo, Russia
N. M. Stel’makh
Ivanovo State University of Chemical Technology
Email: les@isc-ras.ru
153000, Ivanovo, Russia
L. P. Safonova
Krestov Institute of Chemistry of Solutions, Russian Academy of Sciences
Author for correspondence.
Email: les@isc-ras.ru
153045, Ivanovo, Russia
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