Membranes Based on PVdF–HFP and Alkylammonium Protic Ionic Liquids: Thermal and Transport Properties
- 作者: Shmukler L.1, Fadeeva Y.1, Stel’makh N.2, Safonova L.1
-
隶属关系:
- Krestov Institute of Chemistry of Solutions, Russian Academy of Sciences
- Ivanovo State University of Chemical Technology
- 期: 卷 97, 编号 1 (2023)
- 页面: 166-174
- 栏目: ФИЗИЧЕСКАЯ ХИМИЯ ПРОЦЕССОВ РАЗДЕЛЕНИЯ. ХРОМАТОГРАФИЯ
- URL: https://journals.rcsi.science/0044-4537/article/view/136543
- DOI: https://doi.org/10.31857/S0044453723010284
- EDN: https://elibrary.ru/BDDRGU
- ID: 136543
如何引用文章
详细
Casting from a solution is used to obtain proton-conducting membranes based on a poly(vinylidenefluoride-co-hexafluoropropylene) copolymer doped with diethylammonium hydrogen sulfate and diethylammonium mesylate with different levels of doping. An IR spectroscopic study is performed, and the phase behavior of the obtained membranes, their thermal and electrochemical stability, and specific electrical conductivity are investigated. It is established that doping protic ionic liquids into PVdF-HFP copolymer reduces the degree of its crystallinity. It has been shown that all membranes are thermally stable up to 290–300°C, and their conductivity at 145°C varies from 1.6 to 10.4 mS cm–1, depending on the level of doping.
作者简介
L. Shmukler
Krestov Institute of Chemistry of Solutions, Russian Academy of Sciences
Email: les@isc-ras.ru
153000, Ivanovo, Russia
Yu. Fadeeva
Krestov Institute of Chemistry of Solutions, Russian Academy of Sciences
Email: les@isc-ras.ru
153045, Ivanovo, Russia
N. Stel’makh
Ivanovo State University of Chemical Technology
Email: les@isc-ras.ru
153000, Ivanovo, Russia
L. Safonova
Krestov Institute of Chemistry of Solutions, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: les@isc-ras.ru
153045, Ivanovo, Russia
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