Electrocatalytic Reduction of CO2 when Using N-Substituted Salts of 2,4,6-Triphenylpyridine

A. V. Knyazev; Князев А. В.; A. V. Dolganov; Долганов А. В.; L. A. Klimaeva; Климаева Л. А.; S. G. Kostryukov; Кострюков С. Г.; A. Sh. Kozlov; Козлов А. Ш.; A. D. Yudina; Юдина А. Д.; O. V. Tarasova; Тарасова О. В.

doi:10.31857/S0044453723080058

Electrocatalytic Reduction of CO2 when Using N-Substituted Salts of 2,4,6-Triphenylpyridine

Authors: Knyazev A.V.¹, Dolganov A.V.², Klimaeva L.A.², Kostryukov S.G.², Kozlov A.S.², Yudina A.D.², Tarasova O.V.²
Affiliations:
1. Lobachevsky State University
2. Ogarev Mordovian State University
Issue: Vol 97, No 8 (2023)
Pages: 1097-1105
Section: CHEMICAL KINETICS AND CATALYSIS
Submitted: 15.10.2023
Published: 01.08.2023
URL: https://journals.rcsi.science/0044-4537/article/view/136651
DOI: https://doi.org/10.31857/S0044453723080058
EDN: https://elibrary.ru/QTUEON
ID: 136651

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Abstract

A study is performed of the electrocatalytic activity of substituted pyridine salts (N-hydro-, N‑methyl-, and N-phenyl-2,4,6-triphenylpyridinium perchlorates) in the electroreduction of carbon dioxide to carbon monoxide. The effect the natures of the substituent and the H+ source have on the efficiency of the process is determined. The main reasons for the occurrence of the electrocatalytic process are identified, and the values of TOF (catalyst speed) and TON (number of revolutions of the catalyst) are calculated. It is shown that the values of TOF and TON fall as the pK of the acid rises.

Keywords

electrocatalyst, pyridine, reduction, carbon dioxide

References

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