Electrocatalytic Reduction of CO2 when Using N-Substituted Salts of 2,4,6-Triphenylpyridine

A. V. Knyazev; Князев А. В.; A. V. Dolganov; Долганов А. В.; L. A. Klimaeva; Климаева Л. А.; S. G. Kostryukov; Кострюков С. Г.; A. Sh. Kozlov; Козлов А. Ш.; A. D. Yudina; Юдина А. Д.; O. V. Tarasova; Тарасова О. В.

doi:10.31857/S0044453723080058

Electrocatalytic Reduction of CO2 when Using N-Substituted Salts of 2,4,6-Triphenylpyridine

作者: Knyazev A.V.¹, Dolganov A.V.², Klimaeva L.A.², Kostryukov S.G.², Kozlov A.S.², Yudina A.D.², Tarasova O.V.²
隶属关系:
1. Lobachevsky State University
2. Ogarev Mordovian State University
期: 卷 97, 编号 8 (2023)
页面: 1097-1105
栏目: ХИМИЧЕСКАЯ КИНЕТИКА И КАТАЛИЗ
##submission.dateSubmitted##: 15.10.2023
##submission.datePublished##: 01.08.2023
URL: https://journals.rcsi.science/0044-4537/article/view/136651
DOI: https://doi.org/10.31857/S0044453723080058
EDN: https://elibrary.ru/QTUEON
ID: 136651

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详细

A study is performed of the electrocatalytic activity of substituted pyridine salts (N-hydro-, N‑methyl-, and N-phenyl-2,4,6-triphenylpyridinium perchlorates) in the electroreduction of carbon dioxide to carbon monoxide. The effect the natures of the substituent and the H+ source have on the efficiency of the process is determined. The main reasons for the occurrence of the electrocatalytic process are identified, and the values of TOF (catalyst speed) and TON (number of revolutions of the catalyst) are calculated. It is shown that the values of TOF and TON fall as the pK of the acid rises.

关键词

electrocatalyst, pyridine, reduction, carbon dioxide

参考

Liu J.-L., Wang X., Li X.-S. et al. // J. Phys. D: Appl. Phys. 2020. V. 53. № 25. P. 253001.https://doi.org/10.1088/1361-6463/ab7c04
Jenkinson D.S., Adams D.E., Wild A. // Nature. 1991. V. 351. № 6324. P. 304. https://doi.org/10.1038/351304a0.
Weimer T., Schaber K., Specht M. et al. // Energy Conversion and Management/ 1996. V. 370020 № 6–8. P. 1351.https://doi.org/10.1016/0196-8904(95)00345-2
Ren S., Joulié D., Salvatore D. // Science. 2019. V. 365. № 6451. P. 367.https://doi.org/10.1126/science.aax4608
Jin S., Hao Z., Zhang K. // Angewandte Chemie. 2021. V. 133. № 38. P. 20795.https://doi.org/10.1002/ange.202101818
Nielsen D.U., Hu X.-M. // Nat. Catal. 2018. V. 1. № 4. P. 244.https://doi.org/10.1038/s41929-018-0051-3
Hori Y., Wakebe H., Tsukamoto T. et al. // Electrochimica Acta. 1994. № 39. № 11–12. P. 1833.https://doi.org/10.1016/0013-4686(94)85172-7
Gao X., Liang J., Wu L. et al. // Catalysts. 2022. V. 12. № 1. P. 66.https://doi.org/10.3390/catal12010066
Frontera P., Macario A., Ferraro M. et al. // Catalysts. 2017. V. 7. № 12. P. 59.https://doi.org/10.3390/catal7020059
Mikhail M., Wang B., Jalain R. et al. // Reac. Kinet. Mech. Cat. 2019. V. 126. № 2. P. 629–643.https://doi.org/10.1007/s11144-018-1508-8
Zhu D.D., Liu J.L., Qiao S.Z. // Adv. Mater. 2016. V. 28. № 18. P. 3423.https://doi.org/10.1002/adma.201504766
Alberico E., Nielsen M. // Chem. Commun. 2015. V. 51. № 31. P. 6714.https://doi.org/10.1039/C4CC09471A
Dong K., Razzaq R., Hu Y. // Top Curr. Chem. (Z). 2017. V. 375. № 2. P. 23.https://doi.org/10.1007/s41061-017-0107-x
Boutin E., Robert M. // Trends in Chemistry. 2021. V. 3. № 5. P. 359.https://doi.org/10.1016/j.trechm.2021.02.003
Qiao J., Liu Y., Hong F. // Chem. Soc. Rev. 2014. V. 43. № 2. P. 631.https://doi.org/10.1039/C3CS60323G
Zheng Y., Vasileff A., Zhou X. et al. // J. Am. Chem. Soc. 2019. V. 141. № 19. P. 7646.https://doi.org/10.1021/jacs.9b02124
Lim R.J., Xie M., Sk M.A. et al. // Catalysis Today. 2014. V. 233. P. 169.https://doi.org/10.1016/j.cattod.2013.11.037
Specht M. // International Journal of Hydrogen Energy. 1998. V. 23. № 5. P. 387.https://doi.org/10.1016/S0360-3199(97)00077-3
Barton Cole E., Lakkaraju P.S., Rampulla D.M. et al. // J. Am. Chem. Soc. 2010. V. 132. № 33. P. 11539.https://doi.org/0.1021/ja1023496
Dolganov A.V., Tanaseichuk B.S., Pryanichnikova M.K., et al. // J. Phys. Org. Chem. 2019. V. 32. № 5. e3930.https://doi.org/10.1002/poc.3930
Dolganov A.V., Muryumin E.E., Chernyaeva O.Y. et al. // Materials Chemistry and Physics. 2019. V. 224. P. 148.https://doi.org/10.1016/j.matchemphys.2018.12.006
Dolganov A.V., Tanaseichuk, B.S., Tsebulaeva Y.V. et al. // Int. J. Electrochem. Sci. 2016. P. 9559.https://doi.org/10.20964/2016.11.24
Dolganov A.V., Tanaseichuk B.S., Yurova V.Yu. et al. // Intern. J. of Hydrogen Energy 2019. V. 44. № 39. P. 21495.https://doi.org/10.1016/j.ijhydene.2019.06.067
Dolganov A.V., Tanaseichuk B.S., Moiseeva D.N. et al. // Electrochem. Commun., 2016. V. 68. P. 59. https://doi.org/10.1016/j.elecom.2016.04.015
Dolganov A.V., Chernyaeva O.Y., Kostryukov S.G. et al. // Intern. J. of Hydrogen Energy 2020. V. 45. № 1. P. 501.https://doi.org/10.1016/j.ijhydene.2019.10.175
Ganz O.Yu., Klimaeva L.A., Chugunov D.B. et al. // Russ. J. Phys. Chem. 2022. V. 96 № 5. P. 954.https://doi.org/10.1134/S0036024422050120
Klimaeva L.A., Ganz O.Yu., Chugunov D.B. et al. // Russ. J. Phys. Chem. 2022. V. 96. № 5. P. 958.https://doi.org/10.1134/S0036024422050156
Urban J., Volke J. // Collect. Czech. Chem. Commun. 1994. V. 59. № 11. P. 2545.https://doi.org/10.1135/cccc19942545