Electrocatalytic Reduction of CO2 when Using N-Substituted Salts of 2,4,6-Triphenylpyridine
- 作者: Knyazev A.1, Dolganov A.2, Klimaeva L.2, Kostryukov S.2, Kozlov A.2, Yudina A.2, Tarasova O.2
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隶属关系:
- Lobachevsky State University
- Ogarev Mordovian State University
- 期: 卷 97, 编号 8 (2023)
- 页面: 1097-1105
- 栏目: ХИМИЧЕСКАЯ КИНЕТИКА И КАТАЛИЗ
- URL: https://journals.rcsi.science/0044-4537/article/view/136651
- DOI: https://doi.org/10.31857/S0044453723080058
- EDN: https://elibrary.ru/QTUEON
- ID: 136651
如何引用文章
详细
A study is performed of the electrocatalytic activity of substituted pyridine salts (N-hydro-, N‑methyl-, and N-phenyl-2,4,6-triphenylpyridinium perchlorates) in the electroreduction of carbon dioxide to carbon monoxide. The effect the natures of the substituent and the H+ source have on the efficiency of the process is determined. The main reasons for the occurrence of the electrocatalytic process are identified, and the values of TOF (catalyst speed) and TON (number of revolutions of the catalyst) are calculated. It is shown that the values of TOF and TON fall as the pK of the acid rises.
作者简介
A. Knyazev
Lobachevsky State University
Email: dolganov_sasha@mail.ru
Россия, Н.-Новгород
A. Dolganov
Ogarev Mordovian State University
Email: dolganov_sasha@mail.ru
430005, Saransk, Russia
L. Klimaeva
Ogarev Mordovian State University
Email: dolganov_sasha@mail.ru
430005, Saransk, Russia
S. Kostryukov
Ogarev Mordovian State University
Email: dolganov_sasha@mail.ru
430005, Saransk, Russia
A. Kozlov
Ogarev Mordovian State University
Email: dolganov_sasha@mail.ru
430005, Saransk, Russia
A. Yudina
Ogarev Mordovian State University
Email: dolganov_sasha@mail.ru
430005, Saransk, Russia
O. Tarasova
Ogarev Mordovian State University
编辑信件的主要联系方式.
Email: dolganov_sasha@mail.ru
430005, Saransk, Russia
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