Destruction of Octa(4-tert-butylphenyl)tetrapyrazinoporphyrazine Under the Influence of Nitrogen-Containing Organic Bases in Dimethylsulfoxide
- Autores: Petrov O.1, Makarov M.1
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Afiliações:
- Ivanovo State University of Chemistry and Technology
- Edição: Volume 97, Nº 7 (2023)
- Páginas: 938-943
- Seção: ХИМИЧЕСКАЯ КИНЕТИКА И КАТАЛИЗ
- URL: https://journals.rcsi.science/0044-4537/article/view/136613
- DOI: https://doi.org/10.31857/S004445372307021X
- EDN: https://elibrary.ru/SMADUJ
- ID: 136613
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Resumo
A study is performed of the state of octa(4-tert-butylphenyl)tetrapyrazinoporphyrazine in dimethyl sulfoxide. It is found that the acid–base interaction of partner molecules creates a time-stable complex with proton transfer. It is shown that adding morpholine, piperidine, n-butylamine, and diethylamine to dimethyl sulfoxide results in destruction of this complex, in contrast to adding pyridine, 2-methylpyridine, tert-butylamine, or tri-n-butylamine. The effect the proton-acceptor ability and the spatial structure of the base have on the decomposition of the tetrapyrazinoporphyrazine macrocycle is considered.
Sobre autores
O. Petrov
Ivanovo State University of Chemistry and Technology
Email: poa@isuct.ru
153000, Ivanovo, Russia
M. Makarov
Ivanovo State University of Chemistry and Technology
Autor responsável pela correspondência
Email: poa@isuct.ru
153000, Ivanovo, Russia
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