Effect of the Nature of the Solvent on the Formation of Ferrocene Cations during the Protonation of Acetil- and 1,1'-Diacetylferrocene with Perchloric Acid and Their Oxidation with Iodine

V. M. Fomin; Фомин В. М.; N. N. Shuklina; Шуклина Н. Н.

doi:10.31857/S0044453723070105

Effect of the Nature of the Solvent on the Formation of Ferrocene Cations during the Protonation of Acetil- and 1,1'-Diacetylferrocene with Perchloric Acid and Their Oxidation with Iodine

作者: Fomin V.¹, Shuklina N.¹
隶属关系:
1. Lobachevsky State University
期: 卷 97, 编号 7 (2023)
页面: 932-937
栏目: ХИМИЧЕСКАЯ КИНЕТИКА И КАТАЛИЗ
URL: https://journals.rcsi.science/0044-4537/article/view/136611
DOI: https://doi.org/10.31857/S0044453723070105
EDN: https://elibrary.ru/SKONUH
ID: 136611

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详细

It is established that the rate of the formation of ferrocenium cations in reaction mixture acetylferrocene (1,1'-diacetylferrocene) + I2 + HClO4 as a result of the protonation of metal complexes (MCs) and their oxidation with iodine in dioxane and acetonitrile depends on different mechanisms and is described by kinetic equations obtained by analyzing schemes of the process. The observed difference is due to different roles of the protonation of metal complexes and their oxidation with iodine in these solvents.

关键词

acetylferrocene, 1,1'-diacetylferrocene, acid, iodine, protonation, carbocation, redox isomerism, ferrocenium cation, oxidation, kinetic patterns

作者简介

V. Fomin

Lobachevsky State University

Email: niih325@bk.ru
Nizhny Novgorod, Russia

N. Shuklina

Lobachevsky State University

编辑信件的主要联系方式.
Email: niih325@bk.ru
Nizhny Novgorod, Russia

参考

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Фомин В.М., Маркин А.В., Шуклина Н.Н. // ЖОХ. 2020. Т. 90. Вып. 6. С. 896. https://doi.org/10.31857/S0044460X20060091
Фомин В.М., Шуклина Н.Н. // Журн. физ. химии. 2022. Т. 96. № 5. С. 1. https://doi.org/10.31857/S0044453722050119
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