Monitor Calibrator as an Alternative to Spectrofluorimeter: Determination of Quinine in Beverages and Medicinal Preparations
- 作者: Gorbunova M.1, Terentev T.1, Apyari V.1, Dmitrienko S.1, Zolotov Y.1,2
-
隶属关系:
- Department of Chemistry, Lomonosov Moscow State University
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- 期: 卷 78, 编号 3 (2023)
- 页面: 223-230
- 栏目: ОРИГИНАЛЬНЫЕ СТАТЬИ
- ##submission.dateSubmitted##: 14.10.2023
- URL: https://journals.rcsi.science/0044-4502/article/view/135999
- DOI: https://doi.org/10.31857/S0044450223030052
- EDN: https://elibrary.ru/FUJWPC
- ID: 135999
如何引用文章
详细
A possibility of using a monitor calibrator for the determination of luminescent compounds is shown on an example of quinine. The determination is based on the irradiation of a sample with broadband radiation in the visible and near UV spectral regions from a built-in source exciting phosphor molecules and the simultaneous registration of the radiation incident on the detector. Measurement conditions are selected. Quinine can be determined in the range of 60−750 µM, the limit of detection is 20 µM. The determination is not affected by common inorganic ions, as well as sweeteners and acidity regulators present in many beverages. The developed method of determination is applicable to the analysis of carbonated drinks and drugs. Compared to a traditional spectrofluorimeter, monitor calibrator is characterized by compactness, mobility, ability of detecting luminescence in cuvettes of various sizes and shapes, and lower cost.
作者简介
M. Gorbunova
Department of Chemistry, Lomonosov Moscow State University
Email: masha13_1992@mail.ru
119991, Moscow, Russia
T. Terentev
Department of Chemistry, Lomonosov Moscow State University
Email: masha13_1992@mail.ru
119991, Moscow, Russia
V. Apyari
Department of Chemistry, Lomonosov Moscow State University
Email: masha13_1992@mail.ru
119991, Moscow, Russia
S. Dmitrienko
Department of Chemistry, Lomonosov Moscow State University
Email: masha13_1992@mail.ru
119991, Moscow, Russia
Yu. Zolotov
Department of Chemistry, Lomonosov Moscow State University; Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: masha13_1992@mail.ru
119991, Moscow, Russia; 119991, Moscow, Russia
参考
- Апяри В.В., Горбунова М.В., Исаченко А.И., Дмитриенко С.Г., Золотов Ю.А. Использование бытовых цветорегистрирующих устройств в количественном химическом анализе // Журн. аналит. химии. 2017. Т. 72. № 11. С. 963. https://doi.org/10.7868/S0044450217110019
- Моногарова О.В., Осколок К.В., Апяри В.В. Цветометрия в химическом анализе // Журн. аналит. химии. 2018. Т. 73. № 11. С. 857. https://doi.org/10.1134/S0044450218110063
- Lau K.T., Edwards S., Diamond D. Solid-state ammonia sensor based on Berthelot’s reaction // Sens. Actuators B: Chem. 2004. V. 98. № 1. P. 12. https://doi.org/10.1016/j.snb.2003.08.004
- Lapresta-Fernández A., Capitán-Vallvey L.F. Environmental monitoring using a conventional photographic digital camera for multianalyte disposable optical sensors // Anal. Chim. Acta. 2011. V. 706. № 2. P. 328. https://doi.org/10.1016/j.aca.2011.08.042
- Doeven E.H., Barbante G.J., Kerr E., Hogan C.F., Endler J.A., Francis P.S. Red–green–blue electrogenerated chemiluminescence utilizing a digital camera as detector // Anal. Chem. 2014. V. 86. № 5. P. 2727. https://doi.org/10.1021/ac404135f
- Jayawardane B.M., McKelvie I.D., Kolev S.D. A paper-based device for measurement of reactive phosphate in water // Talanta. 2012. V. 100. P. 454. https://doi.org/10.1016/j.talanta.2012.08.021
- Cantrell K., Erenas M.M., de Orbe-Payá I., Capitán-Vallvey L.F. Use of the hue parameter of the hue, saturation, value color space as a quantitative analytical parameter for bitonal optical sensors // Anal. Chem. 2010. V. 82. № 2. P. 531. https://doi.org/10.1021/ac901753c
- Gárcia A., Erenas M.M., Marinetto E.D., Abad C.A., de Orbe-Payá I., Palma A.J., Capitán-Vallvey L.F. Mobile phone platform as portable chemical analyzer // Sens. Actuators B. 2011. V. 156. № 1. P. 350. https://doi.org/10.1016/j.snb.2011.04.045
- Shahvar A., Saraji M., Shamsaei D. Smartphone-based chemiluminescence sensing for TLC imaging // Sens. Actuators B: Chem. 2018. V. 255. P. 891. https://doi.org/10.1016/j.snb.2017.08.144
- Apyari V.V., Dmitrienko S.G., Zolotov Y.A. Unusual application of common digital devices: Potentialities of Eye-One Pro mini-spectrophotometer – A monitor calibrator for registration of surface plasmon resonance bands of silver and gold nanoparticles in solid matrices // Sens. Actuators B: Chem. 2013. V. 188. P. 1109. https://doi.org/10.1016/j.snb.2013.07.097
- Gorbunova M.V., Apyari V.V., Zolotov I.I., Dmitrienko S.G., Garshev A.V., Volkov P.A., Bochenkov V.E. A new nanocomposite optical sensor based on polyurethane foam and gold nanorods for solid-phase spectroscopic determination of catecholamines // Gold Bull. 2019. V. 52. P. 115. https://doi.org/10.1007/s13404-019-00267-9
- Зрелова Л.В., Беляева Е.И., Марченко Д.Ю., Иванова Е.А., Санджиева Д.А., Дедов А.Г. Новый эк-спресс-метод определения гидразида изоникотиновой кислоты в водных растворах с применением отражательной спектрофотометрии и цветометрии // Журн. аналит. химии. 2018. Т. 73. № 3. С. 198. https://doi.org/10.7868/S0044450218030040
- Marchenko D.Y., Petrov S.I., Sandzhieva D.A., Dedov A.G. Express method of the quantitative determination of nitrites by computer colorimetry using new reagent compositions // Theor. Found. Chem. Eng. 2016. V. 50. P. 648. https://doi.org/10.1134/S0040579516040187
- Gorbunova M.V., Evstigneeva P.Yu., Apyari V.V., Dmitrienko S.G. A monitor calibrator as a portable tool for determination of luminescent compounds // IEEE Trans. Instrum. Meas. 2021. V. 70. Article 6002910. https://doi.org/10.1109/TIM.2020.3041390