REE formation in hydrodifluoride processing of the perovskite concentrate


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Abstract

The results of studies of the distribution and forms of existence of rare earth elements in hydrodifluoride leaching of the perovskite concentrate have been presented. It has been established that, in the course of concentrate fluorination, rare earth elements form complex fluoroammonium salts. It has been shown that processing the perovskite concentrate using the fluoride technology enables one to extract 82 of rare earth elements and to obtain a concentrate of rare earth elements that contain oxides with admixtures of fluorides in a few stages.

About the authors

G. F. Krysenko

Institute of Chemistry, Far Eastern Branch

Author for correspondence.
Email: krisenko@ich.dvo.ru
Russian Federation, pr. 100-letya Vladivostoka 159, Vladivostok, 690022

D. G. Epov

Institute of Chemistry, Far Eastern Branch

Email: krisenko@ich.dvo.ru
Russian Federation, pr. 100-letya Vladivostoka 159, Vladivostok, 690022

P. V. Sitnik

Far Eastern Federal University

Email: krisenko@ich.dvo.ru
Russian Federation, ul. Sukhanova 8, Vladivostok, 690950

M. A. Medkov

Institute of Chemistry, Far Eastern Branch

Email: krisenko@ich.dvo.ru
Russian Federation, pr. 100-letya Vladivostoka 159, Vladivostok, 690022

A. I. Nikolaev

Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Science Center

Email: krisenko@ich.dvo.ru
Russian Federation, Akademgorodok 26a, Apatity, Murmansk oblast, 184209

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